Citation: Lu LIU, Mei-Ling CHENG, Li-Zhi-Peng TANG, Zheng LIU, Qi LIU. Mn(Ⅱ)/Ni(Ⅱ) Complexes Based on 5-Methyl-1H-pyrazole-3-carboxylic Acid: Syntheses, Structures, Electrochemical and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1449-1456. doi: 10.11862/CJIC.2021.170 shu

Mn(Ⅱ)/Ni(Ⅱ) Complexes Based on 5-Methyl-1H-pyrazole-3-carboxylic Acid: Syntheses, Structures, Electrochemical and Luminescent Properties

Lu LIU ¹ ,
Mei-Ling CHENG ^1,, ,
Li-Zhi-Peng TANG ¹ ,
Zheng LIU ¹ ,
Qi LIU ^{1, 2}

1.
School of Petrochemical Engineering, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou, Jiangsu 213164, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: Mei-Ling CHENG, chengmeiling01@163.com
Received Date: 22 February 2021
Revised Date: 19 May 2021

Figures(4)

In the absence/presence of chelating N ancillary ligand, 2, 2'-bipyridine (2, 2'-bpy), treatment of 5-methyl-1H-pyrazole-3-carboxylic acid (H₂MPCA) with corresponding Mn(Ⅱ)/Ni(Ⅱ) metal salts afforded two complexes, [Mn(HMPCA)₂(H₂O)₂] (1) and[Ni(HMPCA)₂(2, 2'-bpy)]·2H₂O (2). In mononuclear complexes 1 and 2, each metal ion locates in a distorted octahedral geometry, and the HMPCA^-ligands in 1 and 2 both act as a N, O-chelating ligand. In 1, by the function of intermolecular N—H…O and O—H…O hydrogen bonds, the independent[Mn(HMPCA)₂ (H₂O)₂] units are packed into a porous 3D supramolecular structure with 1D nanotube. In 2, the mononuclear components[Ni(HMPCA)₂(2, 2'-bpy)] and the lattice water molecules are interlinked via intermolecular O—H…O and N—H…O hydrogen bonds, generating a 1D chainlike structure, which is linked to adjacent ones through intermolecular π … π interactions forming a 3D supramolecular architecture. The electrochemical and luminescent properties of complexes 1 and 2 have also been investigated.
- 5-methyl-1H-pyrazole-3-carboxylic acid,
- synthesis,
- crystal structure,
- electrochemical property,
- luminescent
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1.
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