Citation: Ping CHEN, Yi-Ran LIU, Pei-Feng PAN, Ya-Nan FANG, Qi SHAN, Xiao-Miao FENG, Rui-Qing LIU, Xiu-Jing LIN, Yan-Wen MA. Assembly and Application for Li-S Batteries of Multi-walled Carbon Nanotube-Vanadium Nitride Hollow Sphere Composite[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1184-1190. doi: 10.11862/CJIC.2021.150 shu

Assembly and Application for Li-S Batteries of Multi-walled Carbon Nanotube-Vanadium Nitride Hollow Sphere Composite

School of Materials Science & Engineering, Institute of Advanced Materials(IAM), Jiangsu National Synergistic Innovation Center for Advanced Materials(SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: Xiao-Miao FENG, iamxmfeng@njupt.edu.cn
Received Date: 17 December 2020
Revised Date: 25 May 2020

Figures(5)

Multi-walled carbon nanotube/vanadium nitride composite (MWCNT-VN) was used as the positive elec- trode carrier material of lithium - sulfur battery, and sulfur was stored through the hollow structure of vanadium nitride, and it can also effectively limit the shuttle effect of polysulfide. In addition, carbon nanotubes can form a conductive network, which further improves the conductive performance. The initial capacities were 702.2 and 809.3 mAh·g^-1 for VN/S and MWCNT - VN/S cathode at a current density of 1C, respectively. After 350 charge- discharge cycles, the capacity attenuation was about 0.1% per cycle. Compared with pure VN/S, the electrochemical performance of the obtained MWCNT - VN/S was improved, such as high lithium ion mobility, stable rate perfor- mance and excellent long-cycle stability.
- lithium-sulfur batteries,
- vanadium nitride,
- carbon nanotube,
- cathode
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沈阳化工大学材料科学与工程学院沈阳 110142