Citation: Qian ZHANG, Yue-Li WEN, Bin WANG, He-Ming FAN, Chen YANG, Rong-Peng SONG, Wei-Zhong ZHANG, Wei HUANG. Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1390-1398. doi: 10.11862/CJIC.2021.148 shu

Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol

Qian ZHANG ¹ ,
Yue-Li WEN ^1,, ,
Bin WANG ² ,
He-Ming FAN ¹ ,
Chen YANG ¹ ,
Rong-Peng SONG ¹ ,
Wei-Zhong ZHANG ¹ ,
Wei HUANG ^{2, 3,,}

1.
College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
2.
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan 030024, China
3.
Shanxi Taiyuan Coal Conversion Technology Engineering Co., Ltd., Taiyuan 030024, China

Corresponding author: Yue-Li WEN, wenyueli@tyut.edu.cn Wei HUANG, huangwei@tyut.edu.cn
Received Date: 28 January 2021
Revised Date: 25 April 2021

Figures(7)

CuFe@MOFs derived catalysts were synthesized by introducing a second ligand, p-aminobenzoic acid, in the hydrothermal synthesis of MIL-88B(Fe), which was followed by impregnation with Cu species. The physicochemical properties of the catalysts were characterized by X-ray diffraction (XRD), H₂-temperature programmed reduction (H₂-TPR), N₂ adsorption-desorption, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the catalysts for hydrogenation of CO₂ to C₂₊ alcohol (C₂₊OH) was tested in a fixed bed reactor. The results show that the elements of active components were evenly dispersed, and the active species distribution on the catalyst surface can be controlled by adjusting the molar ratio of two ligands (terephthalic acid to p-aminobenzoic acid ligands) in the raw materials. When the molar ratio of terephthalic acid to p-aminobenzoic acid was 5:2, the proportion of low-valence iron of the as-obtained catalyst was the highest (71.27%). Accordingly, this catalyst showed the best performance for CO₂ hydrogenation to C₂₊OH, that the conversion of CO₂ was 8.80%, the selectivity of total alcohol (ROH) was 31.52% and the molar fraction of C₂₊OH was 94.70%. This might be due to the high proportion of low-valence iron species and the well-dispersed active components.
- dual ligand,
- CuFe@MOFs,
- composition control,
- carbon dioxide,
- hydrogenation,
- C₂₊,
- alcohol
1. [1]
  Wang L X, Guan E J, Wang Y Q, Wang L, Gong Z M, Cui Y, Meng X J, Gates B C, Xiao F S. Nat. Commun. , 2020, 11(1): 1033-1042 doi: 10.1038/s41467-020-14817-9
2. [2]
  Xu D, Ding M Y, Hong X L, Liu G L, Tsang S C E. ACS Catal. , 2020, 10(9): 5250-5260 doi: 10.1021/acscatal.0c01184
3. [3]
  JIA C X, SHAO J A, BAI X W, XIAO J J, YANG H P, CHEN H P. Chemical Industry and Engineering Progress, 2020, 39(9): 271-281
4. [4]
  Khan M K, Butolia P, Jo H, Irshad M, Han D, Nam K W, Kim J. ACS Catal. , 2020, 10(18): 10325-10338 doi: 10.1021/acscatal.0c02611
5. [5]
  Li J C, Wang L G, Cao Y, Zhang C J, He P, Li H Q. Chin. J. Chem. Eng. , 2018, 26(11): 2266-2279 doi: 10.1016/j.cjche.2018.07.008
6. [6]
  Gao P, Zhang L N, Li S G, Zhou Z X, Sun Y H. ACS Cent. Sci. , 2020, 6(10): 1657-1670 doi: 10.1021/acscentsci.0c00976
7. [7]
  LI J, JIN B H, YUE H R, YING J K. Applied Chemical Industry, 2016, 45(11): 2005-2008
8. [8]
  Ouyang B, Xiong S, Zhang Y H, Liu B, Li J L. Appl. Catal. A, 2017, 543: 189-195 doi: 10.1016/j.apcata.2017.06.031
9. [9]
  Wang Y, Zhang J J, Qian Q L, Bediako B B A. Green Chem. , 2019, 21: 589-596 doi: 10.1039/C8GC03320J
10. [10]
  Wang P, Bai Y X, Xiao H, Tian S P, Zhang Z Z, Wu Y Q, Xie H J, Yang G H, Han Y Z, Tan Y S. Catal. Commun. , 2016, 75: 92-97 doi: 10.1016/j.catcom.2015.12.012
11. [11]
  Xiang Y, Chitry V, Liddicoat P, Felfer P, Cairmey J, Ringer S, Kruse N. J. Am. Chem. Soc. , 2013, 135(19): 7114-7117 doi: 10.1021/ja402512r
12. [12]
  He Z H, Cui M, Qian Q L, Zhang J J, Liu H Z, Han B X. Proc. Natl. Acad. Sci. U. S. A. , 2019, 116(26): 12654-12659 doi: 10.1073/pnas.1821231116
13. [13]
  Hong Z S, Cao Y, Deng J F, Fan K N. Catal. Lett. , 2002, 82(1): 37-44
14. [14]
  XIANG H, LI J, CAO J X, YANG L. Modern Chemical Industry, 2015, 35(2): 27-31
15. [15]
  FU H, ZHANG M, ZHENG H Y, LI Z. Natural Gas Chemical Industry, 2019, 44(1): 129-134
16. [16]
  Luk H T, Mondeli C, Mitchell S, Curulla F D, Stewart J A, Perez R J. J. Catal. , 2019, 371: 116-125 doi: 10.1016/j.jcat.2019.01.021
17. [17]
  JIANG X Y, RONG N X, QIU T T, QIAN R, WANG Y Z, HAO Q P, HUANG X Q. Chinese J. Inorg. Chem. , 2017, 33(12): 2303-2310 doi: 10.11862/CJIC.2017.222
18. [18]
  LIU C H, GUO X M, ZHONG C L, LI L, HUA Y X, MAO D S, LU G Z. Chinese J. Inorg. Chem. , 2016, 32(8): 1405-1412
19. [19]
  XIN L L, SUN Q, YANG L Y, LI C, MA J F. Tianjin Agricultural Sciences, 2019, 25(4): 80-85
20. [20]
  Shi X P, Yu H B, Gao S, Li X Y, Fang H H, Li R J, Li Y Y, Zhang L J, Liang X L, Yuan Y Z. Fuel, 2017, 20(1): 241-248
21. [21]
  Natesakhawat S, Ohodnicki P J, Howard B, Lekse J, Baltrus J, Mayranga C. Top. Catal. , 2013, 56: 1752-1763 doi: 10.1007/s11244-013-0111-5
22. [22]
  Francielle C F M, Jose M A, Elisabete M A. Mol. Catal. , 2017, 458: 297-306
23. [23]
  Gao W, Zhao Y F, Liu J M, Huang Q W, He S, Li C M, Zhao J W, Wei M. Catal. Sci. Technol. , 2013, 3(5): 1324-1332 doi: 10.1039/c3cy00025g
24. [24]
  Ding J, Zhao W X, Zi L T, Xu X, Liu Q, Zhong Q, Xu Y. Int. J. Hydrogen Energy, 2020, 45(30): 15254-15262 doi: 10.1016/j.ijhydene.2020.03.249
25. [25]
  Liu J H, Zhang G H, Jiang X, Wang J H, Song C S, Guo X W. Catal. Today, 2020, 371(SI): 162-170
26. [26]
  Yu H, Fang C Y, Ji X W, Wei J, Ge Q J, Sun J. ACS Catal. , 2020, 10(20): 12098-12108 doi: 10.1021/acscatal.0c03215
27. [27]
  Reddy G K, Boolchand P, Smirniotis P G. J. Phys. Chem. C, 2012, 116(20): 11019-11031 doi: 10.1021/jp301090d
28. [28]
  Turu Y, Peter H. Appl. Surf. Sci. , 2008, 254: 2441-2449 doi: 10.1016/j.apsusc.2007.09.063
29. [29]
  Shi J J, Hu X M, Madsen M R, Lamagni P, Bjerglund E T, Pedersen S U, Skrydstrup T, Daasbjerg K. ACS Appl. Nano Mater. , 2018, 1(7): 3608-3615 doi: 10.1021/acsanm.8b00755
30. [30]
  Yang C, Zhao H B, Hou Y L, Ma D. J. Am. Chem. Soc. , 2012, 134(38): 15814-15821 doi: 10.1021/ja305048p
31. [31]
  Ramirez A, Gevers L, Bavykina A, Ould-chikh S, Gascon J. ACS Catal. , 2018, 8(10): 9174-9182 doi: 10.1021/acscatal.8b02892
32. [32]
  ZHANG W Z, WEN Y L, SONG R P, WANG B, ZANG Q, HUANG W. Chem. J. Chinese Universities, 2020, 41(6): 1297-1305
33. [33]
  Shigenori U, Hiroaki H, Yoshiyuki H, Hirofumi K, Kunimitsu T, Hideki S, Masahiko A, Masako Y, Sumio I, Kastumi K. J. Phys. Chem. C, 2007, 111(15): 5572-5575 doi: 10.1021/jp071273k
34. [34]
  Mukasyan A S, Roslyakov S, Pauls J M, Gallington L C, Orlova C, Liu X Y, Dobrowolska M, Furdyna J K, Manukyan K V. Inorg. Chem. , 2019, 58(9): 5583-5592 doi: 10.1021/acs.inorgchem.8b03553
35. [35]
  Pan F P, Zhang H G, Liu K X, Cullen D, More K, Wang M Y, Feng Z X, Wang G F, Wu G, Li Y. ACS Catal. , 2018, 8(4): 3116-3122 doi: 10.1021/acscatal.8b00398
36. [36]
  Chang K, Zhang H C, Chen J G, Lu Q, Cheng M J. ACS Catal. , 2019, 9(9): 8197-8207 doi: 10.1021/acscatal.9b01318
37. [37]
  An B, Cheng K, Wang C, Wang Y, Lin W B. ACS Catal. , 2016, 6(6): 3610-3618 doi: 10.1021/acscatal.6b00464
38. [38]
  Zhang M H, Ren J, Yu Y Z. ACS Catal. , 2020, 10(1): 689-701 doi: 10.1021/acscatal.9b03639
39. [39]
  GUO W, GAO W G, WANG H, TIAN J J, HAN C, QIN Z Q. Materials Review, 2013, 27(20): 44-47
40. [40]
  Li S G, Guo H J, Luo C R, Zhang H R, Xiong L, Chen X D, Ma L L. Catal. Lett. , 2013, 143(4): 345-355 doi: 10.1007/s10562-013-0977-7
41. [41]
  Xu D, Ding M Y, Hong X L, Liu G L. ACS Catal. , 2020, 10(24): 14516-14526 doi: 10.1021/acscatal.0c03575
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Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO2 Hydrogenation to C2+ Alcohol

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Effect of Component Control of Catalysts with Dual Ligand CuFe@MOFs as Precursor on Performance of CO₂ Hydrogenation to C₂₊ Alcohol