Citation: Zhong-Xuan XU, Li-Feng LI, Xu-Ling BAI, Shi-Fei XU. Enantiomeric Helical Frameworks with dia Net Based on Rigid Ligands from Spontaneous Resolution[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1191-1196. doi: 10.11862/CJIC.2021.143 shu

Enantiomeric Helical Frameworks with dia Net Based on Rigid Ligands from Spontaneous Resolution

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China

Corresponding author: Zhong-Xuan XU, xuzhongxuan4201@163.com
Received Date: 13 December 2020
Revised Date: 18 April 2020

Figures(6)

The enantiomers of complex 1 (1Δ and 1Λ), [Zn(MPA)(2, 5-DIP)]·1.4H₂O (H₂MPA=2-methoxyterephthalic acid, 2, 5-DIP=2, 5-di(1H-imidazol-1-yl)pyridine) were obtained by spontaneous resolution upon crystallization in the absence of any enantiopure reagents under hydrothermal condition. X-ray crystallography reveals that complexes 1Δ and 1Λ crystallize in chiral space groups P4₁ and P4₃ with near-zero Flack parameters, respectively. In complexes 1Δ and 1Λ, three types of helical chains are constructed by Zn²⁺ ions, MPA^2- and/or 2, 5-DIP ligands along c axis. Although these helical chains contain different components and show different structures, they still have same righthanded helical configuration in 1Δ and left-handed helical configuration in 1Λ, respectively. For the width of channels based on helical chains are up to 1.1 nm×1.1 nm, 1.1 nm×0.8 nm and 0.8 nm×0.8 nm, respectively, and such empty structures result in 5-fold-interpenetrating 3D frameworks with 4-connected dia net in complexes 1Δ and 1Λ. Furthermore, UV-Vis spectra measurement for 1 showed a strong absorption band in ultraviolet region, while solid fluorescence curve revealed blue fluorescence property with emission peak at about 435 nm in complex 1. CCDC: 2049948, 1Δ; 2049947, 1Λ.
- chiral coordination polymers,
- spontaneous resolution,
- helical chain,
- 5-fold-interpenetrating structure,
- dia net
1. [1]
  Mason S F. Nature, 1984, 311: 19-23 doi: 10.1038/311019a0
2. [2]
  Watson J D, Crick F H C. Nature, 1953, 171: 737-738 doi: 10.1038/171737a0
3. [3]
  Halland N, Aburel P S, Jørgensen K A. Angew. Chem. Int. Ed. , 2003, 42(6): 661-665 doi: 10.1002/anie.200390182
4. [4]
  Tan C X, Han X, Li Z J, Liu Y, Cui Y. J. Am. Chem. Soc. , 2018, 140(47): 16229-16236 doi: 10.1021/jacs.8b09606
5. [5]
  Yoon M, Srirambalaji R, Kim K. Chem. Rev. , 2012, 112(2): 1196-1231 doi: 10.1021/cr2003147
6. [6]
  Chandrasekhar P, Mukhopadhyay A, Savitha G, Moorthy J N. Chem. Sci. , 2016, 7(5): 3085-3091 doi: 10.1039/C5SC03839A
7. [7]
  FANG Z L, WANG P, LIU S L, WANG X, NIE Q X, YANG S M, XU W Y, ZHOU M H. Chinese J. Inorg. Chem. , 2020, 36(1): 139-147
8. [8]
  Li P, He Y B, Guan J, Weng L H, Zhao J C G, Xiang S, Chen B. J. Am. Chem. Soc. , 2014, 136(2): 547-549 doi: 10.1021/ja4129795
9. [9]
  Han Q X, He C, Zhao M, Qi B, Niu J Y, Duan C Y. J. Am. Chem. Soc. , 2013, 135(28): 10186-10189 doi: 10.1021/ja401758c
10. [10]
  Dubey M, Kumar A, Dhavale V M, Kurungot S, Pandey D S. CrystEngComm, 2015, 17(43): 8202-8206 doi: 10.1039/C5CE01180A
11. [11]
  Gheorghe A, Tepaske M A, Tanase S. Inorg. Chem. Front. , 2018, 5(7): 1512-1523 doi: 10.1039/C8QI00063H
12. [12]
  JI Q, CHEN L Z. Chinese J. Inorg. Chem. , 2017, 33(5): 874-880
13. [13]
  Gu Z G, Zhang C H, Zhang J, Bu X H. Chem. Soc. Rev. , 2016, 45(11): 3122-3144 doi: 10.1039/C6CS00051G
14. [14]
  Chang C L, Qi X Y, Zhang J W, Qiu Y M, Li X J, Wang X, Bai Y, Sun J L, Liu H W. Chem. Commun. , 2015, 51(17): 3566-3569 doi: 10.1039/C4CC09988E
15. [15]
  Liu Q Y, Xiong W L, Liu C M, Wang Y L, Wei J J, Xiahou Z J, Xiong L H. Inorg. Chem. , 2013, 52(12): 6773-6775 doi: 10.1021/ic400853r
16. [16]
  Yuan S, Deng Y K, Xuan W M, Wang X P, Wang S N, Dou J M, Sun D. CrystEngComm, 2014, 16(19): 3829-3833 doi: 10.1039/c4ce00028e
17. [17]
  Kutzscher C, Nickerl G, Senkovska I, Volodymyr B V, Kaskel S. Chem. Mater. , 2016, 28(8): 2573-2580 doi: 10.1021/acs.chemmater.5b04575
18. [18]
  Wu X, Zhang H B, Xu Z X, Zhang J. Chem. Commun. , 2015, 51(91): 16331-16333 doi: 10.1039/C5CC06501A
19. [19]
  Luo X L, Cao Y, Wang T, Li G H, Yon J G, Yang Y G, Xu Z X, Zhang J, Huo Q S, Liu Y L, Eddaoudi M. J. Am. Chem. Soc. , 2016, 138(3): 786-789 doi: 10.1021/jacs.5b12516
20. [20]
  Xu Z X, Ma Y L, Zhang J. Chem. Commun. , 2016, 52(9): 1923-1925 doi: 10.1039/C5CC09308B
21. [21]
  Sun J W, Zhu J, Song H F, Li G M, Yao X, Yan P F. Cryst. Growth Des. , 2014, 14(11): 5356-5360 doi: 10.1021/cg501211f
22. [22]
  An G H, Yan P F, Sun J W, Li Y X, Yao X, Li G M. CrystEngComm, 2015, 17(24): 4421-4433 doi: 10.1039/C5CE00402K
23. [23]
  Bisht K K, Suresh E. J. Am. Chem. Soc. , 2013, 135(42): 15690-15693 doi: 10.1021/ja4075369
24. [24]
  Yue Q, Wang N N, Guo S Y, Liang L L, Gao E Q. Dalton Trans. , 2016, 45(4): 1335-1338 doi: 10.1039/C5DT04385A
25. [25]
  Mihalcea I, Zill N, Mereacre V, Anson C E, Powell A K. Cryst. Growth Des. , 2014, 14(9): 4729-4734 doi: 10.1021/cg500827u
26. [26]
  Sheldrick G M. Acta Crystallogr. Sect. C, 2015, C71: 3-8
27. [27]
  Speck A L. Acta Crystallogr. Sect. C, 2015, C71: 9-18
28. [28]
  Aexandrov E V, Blatov V A, Kochetkov A V, Proserpio D M. CrystEngComm, 2011, 13(12): 3947-3958 doi: 10.1039/c0ce00636j
29. [29]
  Cui Y J, Yue Y F, Qian G D, Chen B L. Chem. Rev. , 2012, 112(2): 1126-1162 doi: 10.1021/cr200101d
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