Citation: Wen-Bo LIU, Hui DANG, Wen-Ping LIU, Zong-Hua YU, Wei CAO, Kang WANG, Jian-Zhuang JIANG. Ultrathin Porphyrin-Based Covalent Organic Framework Nanosheets for Efficient Photocatalytic Oxidation of Sulfides to Sulfoxides[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1307-1314. doi: 10.11862/CJIC.2021.137 shu

Ultrathin Porphyrin-Based Covalent Organic Framework Nanosheets for Efficient Photocatalytic Oxidation of Sulfides to Sulfoxides

Wen-Bo LIU ¹ ,
Hui DANG ¹ ,
Wen-Ping LIU ¹ ,
Zong-Hua YU ¹ ,
Wei CAO ^2,, ,
Kang WANG ^1,, ,
Jian-Zhuang JIANG ^1,,

1.
Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
2.
State Key Laboratory of NBC Protection for Civilian, Beijing 102205, China

Corresponding author: Wei CAO, vic_cw@126.com Kang WANG, kangwang@ustb.edu.cn Jian-Zhuang JIANG, jianzhuang@ustb.edu.cn
Received Date: 30 January 2021
Revised Date: 30 March 2021

Figures(6)

Singlet oxygen (¹O₂) is an efficient and convenient oxidant for the selective oxidation of sulfides to sulfoxides. It is critical to develop efficient photosensitizers with the high ¹O₂ quantum yield. Herein, we describe the fabrication and characterization of ultrathin two-dimensional covalent organic frameworks (COFs) nanosheets (NSs), COF-367 NSs. In particular, the good dispersibility in various organic solvent and high efficiency in light harvesting of COF-367 NS endow the remarkable performance towards ¹O₂ generation upon irradiation with visible light, much better than the bulk COF-367. We also demonstrate that COF-367 NSs are an excellent heterogeneous catalyst in photocatalytic oxidation of sulfides to sulfoxides with high yield and selectivity as well as good recycling stability.
- covalent organic framework,
- nanosheets,
- singlet oxygen,
- photocatalyst,
- sulfides,
- sulfoxides
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