Citation: Yong-Jun BIAN, Xing-Yu QU, Fen-Fang LI, Zheng-Wei ZHANG, Jian-Qing LI, Yong-Qiang CHEN, Zhen SHEN. Fluorescent Turn-Off Boron Fluoride Dipyrrole Probe for Cu²⁺: Synthesis and Application in Living Cells Imaging[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1089-1096. doi: 10.11862/CJIC.2021.127 shu

Fluorescent Turn-Off Boron Fluoride Dipyrrole Probe for Cu²⁺: Synthesis and Application in Living Cells Imaging

1.
Department of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030619, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Xing-Yu QU, quxy@jzxy.edu.cn Zhen SHEN, zshen@nju.edu.cn
Received Date: 13 February 2021
Revised Date: 28 March 2021

Figures(8)

A fluorescent probe 1, based on boron fluoride dipyrrole (BODIPY) chromophore containing phenyl picolinate as a recognition moiety, was designed, synthesized, and characterized by ¹H NMR, ¹³C NMR, HRMS and X-ray diffraction. Probe 1 had a high fluorescence quantum yield (0.79), and could selectively and sensitively recognize Cu²⁺ from other cations by a fluorescence quenching method. The limit of detection of probe 1 was 0.15 μmol·L^-1. In addition, the recognition mechanism of the fluorescent response to copper ions was verified by HRMS in this work.
- boron fluoride dipyrromethene,
- copper ion,
- fluorescent probe,
- fluorescence quenching
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fluorescent Turn-Off Boron Fluoride Dipyrrole Probe for Cu2+: Synthesis and Application in Living Cells Imaging

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通讯作者: 陈斌, bchen63@163.com

Fluorescent Turn-Off Boron Fluoride Dipyrrole Probe for Cu²⁺: Synthesis and Application in Living Cells Imaging