Citation: Jie LEI, Tao-Xiang WANG, Zhi LI, Hui CHEN, Song YANG, Hai-Bo HAN, Kang LI. Synthesis of Multi-stage Pore Carbon Material with Large Spacing of Carbon Layers from Asphalt for Supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1218-1226. doi: 10.11862/CJIC.2021.126 shu

Synthesis of Multi-stage Pore Carbon Material with Large Spacing of Carbon Layers from Asphalt for Supercapacitors

Jie LEI ¹ ,
Tao-Xiang WANG ¹ ,
Zhi LI ¹ ,
Hui CHEN ² ,
Song YANG ³ ,
Hai-Bo HAN ¹ ,
Kang LI ^1,,

1.
Luoyang R & D Center of Technology of SINOPEC Engineering(Group) Co. Ltd., Luoyang, Henan 471003, China
2.
China Petroleum & Chemical Corporation, Beijing 100027, China
3.
China University of Petroleum(Beijing), Beijing 102249, China

Corresponding author: Kang LI, likang.segr@sinopec.com
Received Date: 3 February 2021
Revised Date: 23 April 2021

Figures(7)

Based on the nanoscale lamellar porous MgO as template, a facile method of petroleum pitch via in-situ KOH activation was designed to obtain multi-stage pore carbon material with large spacing or carbon layers. Meanwhile, the effect of the amount of template on the physicochemical and chemical properties of porous carbon materials, such as pore distribution, carbon layer spacing and electrochemical properties were investigated. The results showed that the specific surface area and pore volume of the carbon material were 2 634 m²·g^-1, 1.12 cm³·g^-1 respectively. What's more, the spacing of carbon layers was 0.374 nm, when the dosage of template was 25% of the quality of asphalt. As electrodes for supercapacitors, 338 F·g^-1 at 1 A·g^-1, 277 F·g^-1 at 20 A·g^-1, and superior cycle stability with 93.5% capacitance retention at 1 A·g^-1 after 10 000 cycles in 6 mol·L^-1 KOH electrolyte, demonstrating excellent electrochemical performance.
- template method,
- spacing of carbon layers,
- lamellar porous MgO,
- specific capacity,
- supercapacitor
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