Citation: Ya-Feng BAI, Zi-Heng YANG, Yong FENG, Fu-Liang LIU, Xiao-Tao CHEN, Ji-Ying CHANG. Preparation and Electrocatalytic Performance of Zn/N Co-doped Carbon Catalyst Derived from MOF[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1055-1061. doi: 10.11862/CJIC.2021.122 shu

Preparation and Electrocatalytic Performance of Zn/N Co-doped Carbon Catalyst Derived from MOF

Ya-Feng BAI ^{1, 2,,} ,
Zi-Heng YANG ^{1, 2} ,
Yong FENG ^{1, 2} ,
Fu-Liang LIU ^{1, 2} ,
Xiao-Tao CHEN ^{1, 2} ,
Ji-Ying CHANG ^{1, 2}

1.
Guizhou Meiling Power Source Co. Ltd., Zunyi, Guizhou 563003, China
2.
State Key Laboratory of Advanced Chemical Power Sources, Zunyi, Guizhou 563003, China

Corresponding author: Ya-Feng BAI, gzmlbyf@163.com
Received Date: 13 January 2021
Revised Date: 14 April 2021

Figures(6)

In order to solve the high cost of fuel cell Pt-based catalysts, nitrogen-doped carbon non-noble metal oxygen reduction reaction (ORR) catalysts have been widely studied. The amorphous Zn(Ⅱ)-organic framework was prepared by solvothermal method and the Zn/N co-doped carbon catalyst was obtained by thermally processing. The results showed that the ZnN/C-900 catalyst (pyrolyzed at 900℃) had a uniform spherical structure. The N₂ adsorption-desorption isotherms of ZnN/C-900 catalyst showed that it had a specific surface area of up to 961 m² g^-1, and the atomic percentages of active N and Zn were 1.6% and 5.87%. The catalyst had high ORR catalytic activity and stability. In alkaline medium, the initial potential, half-wave potential and limiting current density of ZnN/C-900 were 0.955 V, 0.855 V and 7.10 mA·cm^-2, respectively. In acid medium, the initial potential, half-wave potential and limiting current density of ZnN/C-900 were 0.882 V, 0.649 V and 6.01 mA·cm^-2, respectively. ZnN/C-900 exhibited high stability and resistance to methanol poisoning.
- fuel cell,
- oxygen reduction reaction catalyst,
- metal organic framework,
- Zn/N co-doping,
- carbon sphere
1. [1]
  You B, Jiang N, Sheng M L, Drisdell W S, Yano J, Sun Y J. ACS Catal. , 2015, 5(12): 7068-7076 doi: 10.1021/acscatal.5b02325
2. [2]
  Karbhal I, Devarapalli R R, Debgupta J, Pillai V K, Ajayan P M, Shelke M V. Chem. Eur. J. , 2016, 22: 7134-7140 doi: 10.1002/chem.201505225
3. [3]
  Yang L J, Shui J L, Du L, Shao Y Y, Liu J, Dai L M, Hu Z. Adv. Mater. , 2019, 31(13): 1804799 doi: 10.1002/adma.201804799
4. [4]
  Sahraie N R, Paraknowitsch J P, Goebel C, Thomas A, Strasser P. J. Am. Chem. Soc. , 2014, 136(41): 14486-14497 doi: 10.1021/ja506553r
5. [5]
  Wang X X, Swihart M T, Wu G. Nat. Catal. , 2019, 2(7): 578-589 doi: 10.1038/s41929-019-0304-9
6. [6]
  Zhuang L, Zhou S G, Li Y T, Liu T L, Huang D Y. J. Power Sources, 2010, 195(5): 1379-1382 doi: 10.1016/j.jpowsour.2009.09.011
7. [7]
  Zhong H X, Wang J, Zhang Y W, Xu W L, Xing W, Xu D, Zhang Y F, Zhang X B. Angew. Chem. Int. Ed. , 2014, 53(51): 14235-14239 doi: 10.1002/anie.201408990
8. [8]
  Zhang L J, Su Z X, Jiang F L, Yang L L, Qian J J, Zhou Y F, Li W M, Hong M C. Nanoscale, 2014, 6(12): 6590-6602 doi: 10.1039/C4NR00348A
9. [9]
  Jaouen F, Lefèvre M, Dodelet J P, Cai M. J. Phys. Chem. B, 2006, 110(11): 5553-5558 doi: 10.1021/jp057135h
10. [10]
  Bai Y F, Yang D G, Yang M, Chen H B, Liu Y J, Li H M. ChemElectroChem, 2019, 6(9): 2546-2552 doi: 10.1002/celc.201900343
11. [11]
  Yang L J, Tang B B, Wu P Y. J. Mater. Chem. A, 2015, 3(31): 15838-15842 doi: 10.1039/C5TA03507D
12. [12]
  Bennett T D, Cheetham A K. Acc. Chem. Res. , 2014, 47(5): 1555-1562 doi: 10.1021/ar5000314
13. [13]
  Zheng F C, He M N, Yang Y, Chen Q W. Nanoscale, 2015, 7(8): 3410-3417 doi: 10.1039/C4NR06321J
14. [14]
  Bennett T D, Cao S, Tan J C, Keen D A, Bithell E G, Beldon P J, Cheetham A K. J. Am. Chem. Soc. , 2011, 133(37): 14546-14549 doi: 10.1021/ja206082s
15. [15]
  Li Y L, Jia B M, Fan Y Z, Zhu K L, Li G Q, Su C Y. Adv. Energy Mater. , 2018, 8(9): 1702048 doi: 10.1002/aenm.201702048
16. [16]
  Guo Z Y, Zhang Z P, Li Z L, Dou M L, Wang F. Nano Energy, 2019, 57: 108-117 doi: 10.1016/j.nanoen.2018.12.009
17. [17]
  Li J, Chen S G, Yang N, Deng M M, Ibraheem S, Deng J H, Li J, Li L, Wei Z D. Angew. Chem. Int. Ed. , 2019, 58(21): 7035-7039 doi: 10.1002/anie.201902109
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沈阳化工大学材料科学与工程学院沈阳 110142