Citation: Yu SUN, Yun-Po SUN, Chun-Li LIU, Jian XIE, Xin-Bing ZHAO, Lü-Chao QIU, Jian MEI, Xiong-Wen XU, Jian TU. Scalable Preparation and Electrochemical Sodium-Storage Performance of Fe-Based Prussian Blue Cathode Material[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1037-1045. doi: 10.11862/CJIC.2021.116 shu

Scalable Preparation and Electrochemical Sodium-Storage Performance of Fe-Based Prussian Blue Cathode Material

Yu SUN ¹ ,
Yun-Po SUN ¹ ,
Chun-Li LIU ¹ ,
Jian XIE ^1,, ,
Xin-Bing ZHAO ¹ ,
Lü-Chao QIU ² ,
Jian MEI ² ,
Xiong-Wen XU ³ ,
Jian TU ³

1.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
2.
State Grid Zhejiang Electric Power Research Institute, Hangzhou 310014, China
3.
LI-FUN Technology Corporation Limited, Zhuzhou, Hunan 412000, China

Corresponding author: Jian XIE, xiejian1977@zju.edu.cn
Received Date: 8 January 2021
Revised Date: 26 March 2021

Figures(6)

Fe-based Prussian blue material (FePB) was synthesized by coprecipitation method at room temperature using sodium citrate as chelating agent. A high yield of 500 g per preparation can be obtained by using a 20 L reactor and a Na₄Fe(CN)₆ precursor with a concentration up to 0.5 mol·L^-1. The results of electrochemical measurements indicate that the obtained FePB showed a high capacity, excellent rate capability and long cycle life. At 0.1C, the first discharge capacity of FePB reached 117 mAh·g^-1. At a current density as high as 10C, the FePB can still yield a discharge capacity of 92 mAh·g^-1. After 500 cycles at 1C, a specific capacity of 87 mAh·g^-1 still maintained with a retention of 89%. Pouch-type Na-ion full battery was fabricated using commercial hard carbon as anode and FePB as cathode, which exhibited a capacity retention of 75% after 400 cycles at 50 mA. The excellent electrochemical performance of the FePB is attributed to its high sodium content, low defect, border-rich microstructure and the unique open framework structure of the Prussian blue analogues.
- sodium ion battery,
- Prussian blue cathode,
- coprecipitation method,
- scalable preparation,
- electrochemistry,
- energy conversion
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