Citation: Hikmat Ali Mohamad, Karwan Omer Ali, Eric Hosten, Thomas Gerber. Synthesis, Characterization, and X-ray Crystal Structure Analysis of Cu(Ⅰ)/Cu(Ⅱ) Complexes of Phenanthridine and Triphenylphosphine[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1106-1112. doi: 10.11862/CJIC.2021.114 shu

Synthesis, Characterization, and X-ray Crystal Structure Analysis of Cu(Ⅰ)/Cu(Ⅱ) Complexes of Phenanthridine and Triphenylphosphine

1.
Department of Chemistry, College of Education, University of Salahaddin, Erbil, Iraq
2.
Department of Physics, College of Science, University of Halabja, Halabja, Iraq
3.
Department of Chemistry, Faculty of Science, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa

Corresponding author: Hikmat Ali Mohamad, hikmatmohamad@yahoo.com
Received Date: 6 November 2020
Revised Date: 3 April 2021

Figures(6)

Two new complexes of copper(Ⅰ) and copper(Ⅱ) with phenanthridine (Phend) of the following composition : [Cu(κ¹-Phend)₂Cl₂] (1) and [Cu₂(κ¹-Phend)₂(κ¹-PPh₃)₂(μ-Cl)₂] (2) have been prepared in the presence of triphenylphosphine (PPh₃) as a co-ligand. The structures of these complexes have been investigated by elemental analysis, molar conductivity, FT-IR, UV-Vis, and single-crystal X-ray diffraction. X-ray diffraction analysis of typical complex 1 reveals the distorted square planar geometry around copper(Ⅱ) whereas the binuclear complex 2 was irregular tetrahedral geometry around Cu (Ⅰ) center containing bridge Cl^- ion. The FT-IR spectra, elemental analysis as well as UV-Vis spectra confirmed their components, geometries, and ligand interactions. The structures of both complexes have been optimized by density-functional theory (DFT) calculations to explain the electronic spectral properties. CCDC: 1983822, 1; 1983821, 2.
- copper(Ⅰ),
- copper(Ⅱ),
- heteroleptic complex,
- phenanthridine,
- X-ray crystallography,
- density-functional theory computation
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沈阳化工大学材料科学与工程学院沈阳 110142