Citation: Hong-De YE, Xin-Yu ZHANG, Xin XIAO, Qing-Rong ZHU, Lu-Ling HE, Hua-Nan PENG, Zi-Wei LIU. Reactivity of Half-Sandwich 16e Carborane Compound Cp^*CoS₂C₂B₁₀H₁₀ with Phosphorous Compounds[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1375-1380. doi: 10.11862/CJIC.2021.109 shu

Reactivity of Half-Sandwich 16e Carborane Compound Cp^*CoS₂C₂B₁₀H₁₀ with Phosphorous Compounds

Hong-De YE ^{1, 2,,} ,
Xin-Yu ZHANG ¹ ,
Xin XIAO ¹ ,
Qing-Rong ZHU ¹ ,
Lu-Ling HE ¹ ,
Hua-Nan PENG ^1,, ,
Zi-Wei LIU ¹

1.
Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Environmental Science, Shangrao Normal University, Shangrao, Jiangxi 334001, China
2.
Key Laboratory of Tropical Medicinal Plant Chemistry of Hainan Province, Hainan Normal University, Haikou 571158, China

Corresponding author: Hong-De YE, yehongde@163.com Hua-Nan PENG, huananpeng@126.com
Received Date: 14 December 2020
Revised Date: 3 February 2021

Figures(6)

Half-sandwich 16e carborane compound Cp^*CoS₂C₂B₁₀H₁₀ reacts with diphenylmethylphosphine, phenyl-dimethylphosphine and trimethylphosphine to afford addition compounds (Cp^*CoS₂C₂B₁₀H₁₀) (PPh₂Me) (1), (Cp^*CoS₂C₂B₁₀H₁₀) (PPhMe₂) (2) and (Cp^*CoS₂C₂B₁₀H₁₀) (PMe₃) (3), respectively. 1, 2 and 3 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis. The ultraviolet spectra of compounds 1, 2 and 3 in acetonitrile showed two absorb bands, where the first bands were located at 321, 316 and 321 nm, respectively, and the second bands were located at 425, 399 and 407 nm, respectively. The fluorescence spectrum results of compounds 1, 2 and 3 exhibited maximum emission peaks at about 406 nm.
- half-sandwich,
- carborane,
- phosphorous compounds
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沈阳化工大学材料科学与工程学院沈阳 110142

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Reactivity of Half-Sandwich 16e Carborane Compound Cp^*CoS₂C₂B₁₀H₁₀ with Phosphorous Compounds