Citation: Wen-Li CUI, Lin AN, Qing-Hong ZHANG, Hong-Zhi WANG, Yao-Gang LI, Cheng-Yi HOU. FeNi Layered Double Hydroxide/TiO₂ Composite Photocatalyst: Preparation and Hydrogen Production Performance[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 867-874. doi: 10.11862/CJIC.2021.108 shu

FeNi Layered Double Hydroxide/TiO₂ Composite Photocatalyst: Preparation and Hydrogen Production Performance

School of Materials Science and Engineering, Donghua University, Shanghai 201620, China

Corresponding author: Qing-Hong ZHANG, zhangqh@dhu.edu.cn
Received Date: 29 December 2020
Revised Date: 24 March 2021

Figures(10)

Layered double hydroxide (LDH) photogenerated electron-hole pairs are easy to recombine. Although the unique structure of nanosheets promotes the separation of carriers, the photocatalytic efficiency is still low. In this paper, taking advantage of its thin-film structure, FeNi LDH was combined with TiO₂ by electrostatic self-assembly method to design and prepare efficient FeNi LDH/TiO₂ composite photocatalysts, and evaluated its hydrogen production performance. Their structure, photocatalytic performance and photoelectrochemistry were characterized in detail. The results showed that the high specific surface area of FeNi LDH and the heterojunction structure of the composite were all conducive to photo-generated charge transfer. The results of photocatalytic hydrogen production showed that the hydrogen production rate (22.6 mmol·g^-1·h^-1) of FeNi LDH/TiO₂ composite was 226 and 452 times higher than that of bare TiO₂ (0.1 mmol·g^-1·h^-1) and FeNi LDH (0.05 mmol·g^-1·h^-1) respectively, indicating the crucial role of heterojunction in improving the photocatalytic efficiency of LDH.
- FeNi layered double hydroxide,
- electrostatic self-assembly,
- heterojunction,
- photocatalytic hydrogen production
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FeNi Layered Double Hydroxide/TiO2 Composite Photocatalyst: Preparation and Hydrogen Production Performance

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FeNi Layered Double Hydroxide/TiO₂ Composite Photocatalyst: Preparation and Hydrogen Production Performance