Citation: Qi WANG, Ya-Xin SI, Tian YANG, Ying-Xi GAO, Xiao-Feng GAO, Bin ZHU, Chun-Lei MA. Synthesis of Carbon Dots-Manganese Dioxide Nanocomposite and Fluorescent Sensing of Tiopronin[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 995-1003. doi: 10.11862/CJIC.2021.107 shu

Synthesis of Carbon Dots-Manganese Dioxide Nanocomposite and Fluorescent Sensing of Tiopronin

Chemistry & Chemical Engineering Department, Taiyuan Institute of Technology, Taiyuan 030008, China

Corresponding author: Qi WANG, wangq@tit.edu.cn Chun-Lei MA, macl@tit.edu.cn
Received Date: 18 December 2020
Revised Date: 29 March 2021

Figures(7)

Herein, fluorescent carbon dots (CDs) were synthesized through a hydrothermal method using poly (allylamine hydrochloride) as reaction substrate. After introduce of potassium permanganate, CDs-MnO₂ nanocomposite were prepared through an in situ redox reaction. The as-prepared nanomaterials were characterized by transmission electron microscope, X-ray photoelectron spectroscopy, nanometer size analysis, ultraviolet-visible absorption spectrum, fluorescence spectrum, and fluorescence lifetime. It was demonstrated that the MnO₂ quenched the fluorescence intensity of CDs through static quenching effect (SQE) and inner filter effect (IFE). Further, taking advantage of active thiol in its molecule, tiopronin (TPN) decomposed MnO₂ through a unique redox reaction, which made the quencher disappeared and thus restored the fluorescence. Therefore, a CDs-MnO₂ nanocomposite based fluorescent sensor was established to detect tiopronin. This method showed good sensitivity and selectivity for TPN. The linear range was 0.2~80 μmol·L^-1 with a detection limit of 0.11 μmol·L^-1. The MnO₂ nanomaterials mediated fluorescence method was applied for the TPN detection in urine sample and the recovery was in the range of 97.57%~102.58%.
- carbon dots,
- manganese dioxide,
- fluorescent sensing,
- tiopronin
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