Citation: Shao-Ying JU, Xue LI, An-Li GAO, Jing JIANG, Juan YU, Wei-Ping LIU. Synthesis, Structure and Catalytic Activity of Three Organophosphine Bromo Palladium(Ⅱ) Complexes for Coupling Reactions[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 785-790. doi: 10.11862/CJIC.2021.102 shu

Synthesis, Structure and Catalytic Activity of Three Organophosphine Bromo Palladium(Ⅱ) Complexes for Coupling Reactions

State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China

Corresponding author: Juan YU, liuweiping1963@126.com Wei-Ping LIU, juanyu1210@126.com
Received Date: 1 September 2020
Revised Date: 23 March 2021

Figures(2)

Three new palladium(Ⅱ) complexes with Br^- as the dissociation ligand and with di-tert-butylphenyl phosphine((t-Bu)₂PPh), di-tert-butyl-(4-dimethylaminophenyl)phosphine (Amphos) or 4, 5-bis(diphenyl-phosphino)-9, 9-dimethylxanthene (Xantphos) as the organic phosphine ligand, were prepared from the starting material PdBr₂ via the coordination addition and ligand substitution process, with an attempt to develop more effective organophosphinopalladium catalysts for the coupling reactions. The palladium (Ⅱ) complexes were tested and characterized by elemental analysis, ¹H NMR and single-crystal X-ray diffraction analysis to be trans-Pd((t-Bu)₂PPh)₂Br₂ (1), trans-[Pd(Amphos)Br₂]₂ (2), cis-Pd(Xantphos)Br₂ (3). Among them, trans-[Pd(Amphos)Br₂]₂ is a unique binuclear palladium complex in which two bromine ions act as the bridging ligand bringing two[Pd(Amphos)Br] blocks together. Two typical Suzuki organic coupling reaction models were used for evaluating the catalytic activity of three complexes along with commercially available Pd((t-Bu)₂PPh)₂Cl₂, Pd(Amphos)₂Cl₂ and Pd(Xantphos)Cl₂ as comparison catalysts. The results showed all three complexes displayed high catalytic activity in two selected typical Suzuki organic coupling reactions, greater than the corresponding values of Pd((t-Bu)₂PPh)₂Cl₂, Pd(Amphos)₂Cl₂ and Pd(Xantphos)Cl₂.
- organophosphine ligand,
- bromine ligand,
- palladium(Ⅱ) complex,
- structure,
- catalytic activity
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