Citation: Jin-Jian LIU, Na LIU, Yi-Wei LU, Guo-Zheng ZHAO. Three Photochromic Co-crystals Based on Viologen Moiety[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 937-944. doi: 10.11862/CJIC.2021.100 shu

Three Photochromic Co-crystals Based on Viologen Moiety

Jin-Jian LIU ^{1, 2,,} ,
Na LIU ² ,
Yi-Wei LU ² ,
Guo-Zheng ZHAO ²

1.
Modern College of Humanities and Science, Shanxi Normal University, Linfen, Shanxi 041000, China
2.
School of Chemistry and Material Science, Shanxi Normal University, Linfen, Shanxi 041004, China

Corresponding author: Jin-Jian LIU, liujj@sxnu.edu.cn
Received Date: 25 November 2020
Revised Date: 5 January 2021

Figures(4)

The reactions of 1, 2, 4, 5-benzenetetracarboxylic acid (H₄BTEC) with the transition metal ions in the presence of neutral viologen moiety, 1-carboxyethyl-4, 4'-bipyridine (CEbpy), led to three isostructural co-crystals[M(H₂O)₅(BTEC)_0.5]·(CEbpy) (M=Mn (1), Zn (2), Co (3)) in an alkaline environment. Upon UV irradiation, these three compounds exhibited obvious photochromic behaviors owing to the formation of viologen radicals through photo-induced electron transfer. Meanwhile, compound 3 exhibited irreversible hydrochromic behavior upon heating, while compounds 1 and 2 did not. The influence of metal ions on their chromic behaviors has been discussed. CCDC: 1953749, 1; 1954911, 2; 2032783, 3.
- 1-carboxyethyl-4, 4'-bipyridine (CEbpy),
- co-crystals,
- photochromism,
- hydrochromism
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