Citation: Yu LI, Ying-Fen ZHUANG, Yan-Lai ZHANG, An-Sheng FENG, Xun-Zhong ZOU. Synthesis and Characterization of Palladium Nanoparticles with High Proportion of Exposed (111) Facet for Hydrogenation Performance[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(6): 1143-1151. doi: 10.11862/CJIC.2021.095 shu

Synthesis and Characterization of Palladium Nanoparticles with High Proportion of Exposed (111) Facet for Hydrogenation Performance

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: Xun-Zhong ZOU, xhyan@zjut.edu.cn
Received Date: 19 December 2020
Revised Date: 16 March 2021

Figures(8)

Pd nanoparticles with different (111) facet proportions were prepared at by a liquid phase hydrogen reduction method, then preparing corresponding Pd/C catalysts. The results of transmission electron microscopy (TEM), fast Fourie transition (FFT), and X-ray diffraction (XRD) revealed that the proportion of the (111) facets on the Pd surface was higher at lower temperatures. Hydrogen oxygen pulse titration (H₂-O₂) and H₂-temperature programmed desorption (H₂-TPD) showed that the hydrogen adsorption volume of Pd/C catalysts was correlated linearly with the Pd(111) facet proportions. All Pd/C catalysts had an average particle size of 4.3 nm with narrow particle size distribution, which could eliminated the effect of particle size. The similar pore parameters and Pd loading of all catalysts allowed the reasonable comparison for Pd(111) facet proportions influenced the hydrogenation performance in three typical reactions. Moreover, linear correlations were found between the H₂ consumption rate with Pd (111) facet proportions in each of styrene, cyclohexene, and p-nitrotoluene hydrogenation. The good catalytic performance of high Pd(111) facet proportion catalyst for hydrogenations could be attributed to the H₂ molecule prior to absorbed the Pd(111) facet promoting the formation of dissociated hydrogen atoms. These results above indicated that Pd-based catalysts with high (111) facet proportion facilitated hydrogenation performance.
- palladium,
- single crystal,
- Pd(111) facet,
- hydrogen dissociation,
- hydrogenation
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