Citation: Lao-bang WANG, Ji-jiang WANG, Er-lin YUE, Long TANG, Xiao WANG, Xiang-yang HOU, Yu-qi ZHANG. Synthesis, Structure, Magnetic and Photocatalytic Properties of Nickel(Ⅱ) Coordination Polymer Based on 1-(3,5-Dicarboxybenzyl)-1H-pyrazole-3,5-dicarboxylic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 744-750. doi: 10.11862/CJIC.2021.089 shu

Synthesis, Structure, Magnetic and Photocatalytic Properties of Nickel(Ⅱ) Coordination Polymer Based on 1-(3,5-Dicarboxybenzyl)-1H-pyrazole-3,5-dicarboxylic Acid Ligand

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  • A new coordination polymer {[Ni2(L)(bib)1.5(H2O)4]·3H2O}n (1)(H4L=1-(3,5-dicarboxybenzyl)-1H-pyrazole-3,5-dicarboxylic acid, bib=1,4-bis(1-imidazolyl)benzene) was synthesized by hydrothermal method and characterized by single-crystal X-ray diffraction, elemental analyses and thermogravimetric analysis. Complex 1 features a 3D network structure. The variable temperature magnetic susceptibility measurements reveal that there are antiferromagnetic interactions between the Ni(Ⅱ) ions in complex 1. In addition, photocatalytic experiments indicated that complex 1 exhibited high photocatalytic activity up to 82.7% for the degradation of methylene blue pollutant.CCDC: 2030837.
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