Citation: Xiao-qiang LI, Xin CHEN, Hong-bo LI, Ting-ting ZHAO, Ya-mei ZHANG, Jun XIANG, Kai-yin ZHANG. Carbon-Coated CaSnO₃ Nanofibers as High Performance Anode Materials for Lithium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 700-708. doi: 10.11862/CJIC.2021.085 shu

Carbon-Coated CaSnO₃ Nanofibers as High Performance Anode Materials for Lithium Ion Batteries

1.
School of Science, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China
2.
Wuyi University, Wuyishan, Fujian 354399, China

Corresponding author: Jun XIANG, jxiang@just.edu.cn
Received Date: 1 December 2020
Revised Date: 30 January 2021

Figures(9)

Carbon coated CaSnO₃ nanofibers(denoted as CaSnO₃@C NFs) were prepared via the electrospinning technique combined with in-situ polymerization and carbonization processes. The phase compositions, surface morphology and microstructures of the samples were characterized by means of X-ray diffraction, scanning electron microscope, transmitting electron microscope and X-ray photoelectron spectroscopy. The influences of carbon coating and carbonization temperature on the electrochemical properties of CaSnO₃ NFs-based anode materials were investigated using cyclic voltammetry, galvanostatic charge/discharge and AC impedance spectroscopy. The test results show that the electrochemical performance of CaSnO₃ NFs was greatly improved after carbon coating, and meanwhile the specific capacity of CaSnO₃@C NFs composites first increased and then decreased with increasing carbonization temperature, in which the CaSnO₃@C NFs-600 composite obtained by carbonization at 600 ℃ exhibited an optimal electrochemical performance. The CaSnO₃@C NFs-600 electrode had a high initial discharge specific capacity of 1 102.2 mAh·g^-1 at a current density of 100 mA·g^-1, and delivered a reversible specific capacity of 548.8 mAh·g^-1 after 100 charge/discharge cycles. Moreover, it also showed a superior rate performance and retained a specific capacity of 333.5 mAh·g^-1 even at 2 A·g^-1.
- CaSnO₃ nanofibers,
- carbon coating,
- electrospinning,
- anode material,
- lithium storage performance
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沈阳化工大学材料科学与工程学院沈阳 110142

Carbon-Coated CaSnO3 Nanofibers as High Performance Anode Materials for Lithium Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Carbon-Coated CaSnO₃ Nanofibers as High Performance Anode Materials for Lithium Ion Batteries