Citation: Xin HE, Shun-Lin ZHANG, Tian-Yu XIAO, Dun-Ru ZHU. Two Metal-Organic Frameworks Built from 2, 2'-Dimethyl-4, 4'-biphenyldicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 945-952. doi: 10.11862/CJIC.2021.079 shu

Two Metal-Organic Frameworks Built from 2, 2'-Dimethyl-4, 4'-biphenyldicarboxylic Acid

Xin HE ¹ ,
Shun-Lin ZHANG ¹ ,
Tian-Yu XIAO ¹ ,
Dun-Ru ZHU ^{1, 2,,}

1.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: Dun-Ru ZHU, zhudr@njtech.edu.cn
Received Date: 6 December 2020
Revised Date: 24 December 2020

Figures(8)

Two metal-organic frameworks (MOFs), [Ni(μ₂-H₂O)(L)(DMF)(H₂O)]·0.5H₂O (1) and[Cd_2.5(L)(trz)₃(H₂O)₂]·2.5DMF (2) (L=2, 2'-dimethyl-4, 4'-biphenyldicarboxylic acid, DMF=N, N-dimethylformamide, Htrz=1, 2, 4-triazole), have been synthesized and characterized by FT-IR, thermogravimetric analysis (TGA), powder and single crystal X-ray diffraction. MOF 1 crystallizes in monoclinic system with a space group P2₁/c. Ni(Ⅱ) ion adopts an elongated[NiO₆] octahedron as a 4-connected node and is linked by μ₂-H₂O and L^2- ligands to generate a 2D sql topological network. MOF 2 crystallizes in monoclinic system with a space group C2/m and contains three crystallographically different Cd(Ⅱ) ions. Each Cd(Ⅱ) ion shows a distorted octahedral geometry and three Cd(Ⅱ) ions are connected by trz^- co-ligands in a μ_{1, 2, 4}-bridging mode to form a 2D kgd layer with (3, 6) topology in the ab plane. These layers are further pillared by the L^2- ligands along the c axis to produce a binodal (4, 8)-connected 3D flu framework. The TGA showed that 1 and 2 were stable below 390 and 230℃, respectively. CCDC: 2042076, 1; 2042077, 2.
- metal-organic frameworks,
- 2, 2'-dimethyl-4, 4'-biphenyldicarboxylic acid,
- crystal structure,
- topology
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