Citation: Fang DU, Shuai LIU, Jing-Jiu GU, Heng WANG, Bing LI. Effect of Mass Ratio of Ni and Co in Initial Solution on Oxygen Evolution Reaction Performance of Ni-Co-S-O/NF Catalyst in Alkaline Water Electrolysis[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 929-936. doi: 10.11862/CJIC.2021.076 shu

Effect of Mass Ratio of Ni and Co in Initial Solution on Oxygen Evolution Reaction Performance of Ni-Co-S-O/NF Catalyst in Alkaline Water Electrolysis

Fang DU ¹ ,
Shuai LIU ¹ ,
Jing-Jiu GU ¹ ,
Heng WANG ¹ ,
Bing LI ^{1, 2,,}

1.
School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai 200237, China
2.
Collaborative Innovation Center of Clean Energy, Longyan University, Longyan, Fujian 364012, China

Corresponding author: Bing LI, bingli@ecust.edu.cn
Received Date: 24 November 2020
Revised Date: 20 January 2021

Figures(8)

In this paper, the effect of mass ratio of Ni and Co (w_Ni: w_Co) in initial solution on the structure and properties of Ni-Co-S-O composite catalysts was studied. A three-dimensional petal-like and hierarchically connected nano-structured Ni-Co-S-O composite catalyst was obtained on a nickel foam (NF) substrate by a hydrothermal method. When w Ni: w_Co=1:2, the prepared Ni-Co-S-O/NF(1:2) catalyst has a larger electrochemically active area (ECSA) and the best oxygen evolution reaction (OER) catalytic performance in alkaline water electrolysis. In 1 mol·L^-1 KOH alkaline solution, Ni-Co-S-O/NF(1:2) only need 61 and 313 mV to achieve the current density of 10 and 100 mA·cm^-2 respectively. At the same time, its Tafel slope was 155 mV·dec^-1. After tested at a high current density of 100 mA·cm^-2 for 24 h in the alkaline solution, the Ni-Co-S-O/NF(1:2) could still maintain sheet structure and displayed a good durability.
- Ni-Co-S-O/NF catalyst,
- alkaline water electrolysis,
- oxygen evolution reaction,
- transition metal
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