Citation: Xue-lan MEI, Jian-ni GUO, Min-jie DU, Pei-pei YANG, Qian LI, Zong-qun LI, An-rong JU. Three Binuclear Lanthanide Complexes Constructed from Nitronyl Nitroxide Radical Ligands Containing Phenol Groups: Structure and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 592-600. doi: 10.11862/CJIC.2021.073 shu

Three Binuclear Lanthanide Complexes Constructed from Nitronyl Nitroxide Radical Ligands Containing Phenol Groups: Structure and Magnetic Properties

Xue-lan MEI ^1,, ,
Jian-ni GUO ² ,
Min-jie DU ³ ,
Pei-pei YANG ^4,, ,
Qian LI ¹ ,
Zong-qun LI ¹ ,
An-rong JU ¹

1.
College of Materials Science and Chemical Engineering, Bengbu University, Anhui 233030, China
2.
Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
3.
Military Representative Bureau of Nanjing of the PLA Army, Bengbu, Anhui 233030, China
4.
College of Chemistry and Materials Science, Huaibei Normal University, Huaibei, Anhui 235000, China

Corresponding author: Xue-lan MEI, daluhuashu@qq.com Pei-pei YANG, 394117773@qq.com
Received Date: 15 August 2020
Revised Date: 30 December 2020

Figures(10)

The nitronyl nitroxide radicals NIT-5Br-2PhOH(2-(2′-hydroxy-5′-bromophenyl)-4, 4, 5, 5-tetramethylimidazoline-1-oxyl-3-oxide) and NIT-5NO₂-2 PhOH(2-(2′-hydroxy-5′-nitrophenyl)-4, 4, 5, 5-tetramethylimidazoline-1-oxyl-3-oxide) were selected as ligands to react with Ln(tfac)₃·2H₂O(tfac=trifluoroacetylacetonate) to produce three new lanthanide-radical complexes [Ln(tfac)₂(NIT-5Br-2PhO)]₂(Ln=Gd(1), Dy(2)) and [Dy(tfac)₂(NIT-5NO₂-2 PhO)]₂(3).Single crystal X-ray crystallographic analysis reveals that all three complexes possess binuclear structure in which two lanthanide ions are connected through the hydroxy groups of the radicals. DC magnetic susceptibilities of Gd complex reveal that the antiferromagnetic coupling between the Gd(Ⅲ) centers plays a major role for the magnetic behavior. CCDC: 1981623, 1; 1981622, 2; 2021836, 3.
- lanthanide complexes,
- nitronyl nitroxide radical,
- binuclear structure,
- magnetic behavior
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