Citation: Zhou-rong XIAO, Qian-cheng ZHENG, Xiang-wen ZHANG, Ling LI, Li WANG, Guo-zhu LI. Synthesis of Ni-Co Catalysts Supported on Flower-like MgAl Composite Oxide for Hydrogen Production by n-Dodecane Steam Reforming[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 629-637. doi: 10.11862/CJIC.2021.069 shu

Synthesis of Ni-Co Catalysts Supported on Flower-like MgAl Composite Oxide for Hydrogen Production by n-Dodecane Steam Reforming

Zhou-rong XIAO ¹ ,
Qian-cheng ZHENG ¹ ,
Xiang-wen ZHANG ^{1, 2} ,
Ling LI ³ ,
Li WANG ^{1, 2} ,
Guo-zhu LI ^{1, 2,,}

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
2.
Collaborative Innovation Center of Chemical Science & Engineering, Tianjin University, Tianjin 300072, China
3.
HBIS Chengde Steel Vanadium and Titanium Division, Chengde, Hebei 067000, China

Corresponding author: Guo-zhu LI, gzli@tju.edu.cn
Received Date: 4 October 2020
Revised Date: 10 December 2020

Figures(13)

Flower-like Ni-Co-Mg-Al layered hydrotalcite materials were prepared by a hydrothermal crystallization method. After high-temperature calcination and hydrogen reduction, a series of Ni-Co alloy catalysts supported on MgAl composite oxides were successfully prepared. The physicochemical properties of the catalysts were characterized by scanning electron microscopy, transmission electron microscopy, nitrogen adsorption-desorption test, powder X-ray diffraction and temperature programmed reduction. The catalysts were tested for hydrogen production from steam reforming of n-dodecane. The results show that the precursor of hydrothermal crystallization catalyst was spherical flower-like layered hydrotalcite structure, and the as-calcined catalyst was in the form of composite oxide with abundant mesopores and macropores. The metal-support interaction and particles size of metal can be controlled by adjusting the amount of Co added. After reduction, Ni and Co formed an alloy and distributed uniformly on the lamellar MgAl composite oxide. Compared with the catalyst of single-metal Ni, the activity and hydrogen production rate of Ni-Co alloy catalyst were greatly improved, and the coke resistance was greatly improved. This is due to the synergistic effects of Ni-Co alloy and small metal nanoparticles.
- hydrotalcite,
- nickel-cobalt alloy,
- catalysis,
- n-dodecane,
- steam reforming,
- hydrogen production
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