Citation: Xin-li JIA, Jian-hui LUO, Ping-mei WANG, Mei-ying HE, Yi-han WANG, Pei-wen XIAO, Bo JIANG. Synthesis of Dumbbell-like SiO₂ Nanoparticles with Amphiphilic Properties in Aqueous Phase[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 653-660. doi: 10.11862/CJIC.2021.061 shu

Synthesis of Dumbbell-like SiO₂ Nanoparticles with Amphiphilic Properties in Aqueous Phase

Xin-li JIA ¹ ,
Jian-hui LUO ^{2, 3} ,
Ping-mei WANG ^{2, 3} ,
Mei-ying HE ¹ ,
Yi-han WANG ¹ ,
Pei-wen XIAO ^{2, 3} ,
Bo JIANG ^1,,

1.
Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China
2.
Research Institute of Petroleum Exploration & Development(RIPED), Petro China, Beijing 100083, China
3.
Key Laboratory of Nano Chemistry(KLNC), Petro China, Beijing 100083, China

Corresponding author: Bo JIANG, jiangbo@scu.edu.cn
Received Date: 17 October 2020
Revised Date: 7 January 2021

Figures(10)

Anisotropic SiO₂ nanoparticles with dumbbell-like structure were prepared from nano SiO₂ hydrosol in aqueous phase by a simple chemical process. Nano SiO₂ hydrosol were previously modified with 3-aminopropyl triethoxysilane(APTES) and 3-chloropropyl triethoxysilane(CPTES), respectively. The APTES and CPTES modified SiO₂ hydrosol were then mixed with different proportions, the SiO₂ nanoparticles coupled to form dumbbell-like particles with a particle size of about 45 nm via the reaction of amine group and chloropropyl groups grafted on the surface of silica. The morphology, structure and chemical performance of SiO₂ nanoparticles were systematically characterized by transmission electron microscopy(TEM), Fourier transform infrared(FT-IR), X-ray photoelectron spectroscopy(XPS) and dynamic light scatering(DLS). As a result, the dumbbell-like SiO₂ nanoparticles with different hydrophilicity on both sides were successfully prepared, and the particle size was approximately equal to the sum of the particle size of APTES modified SiO₂ particles and CPTES modified SiO₂ particles.
- dumbbell-like SiO₂ nanoparticles,
- silane coupling agent,
- surface modification,
- aqueous phase
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Dumbbell-like SiO2 Nanoparticles with Amphiphilic Properties in Aqueous Phase

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Dumbbell-like SiO₂ Nanoparticles with Amphiphilic Properties in Aqueous Phase