Citation: Tong CHANG, Hao-tong NIU, Rui-jing MA, Hui-xiang WANG, Bao-liang LU:. Photocatalytic Degradation of Quasi-phenothiazine Dyes by Fe Species Modified Urchin-like Nb₂O₅ Nanospheres[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(4): 717-727. doi: 10.11862/CJIC.2021.060 shu

Photocatalytic Degradation of Quasi-phenothiazine Dyes by Fe Species Modified Urchin-like Nb₂O₅ Nanospheres

Tong CHANG ^{1, #} ,
Hao-tong NIU ^{2, 3, #} ,
Rui-jing MA ⁴ ,
Hui-xiang WANG ^2,, ,
Bao-liang LU: ^{1, 2,,}

1.
Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China
2.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Science, Taiyuan 030001, China
3.
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
4.
Department of Physics and Electronic Engineering, Yuncheng University, Yuncheng, Shanxi 044000, China

Corresponding author: Hui-xiang WANG, wanghx@sxicc.ac.cn Bao-liang LU:, lbl604@sxicc.ac.cn
Received Date: 1 December 2020
Revised Date: 6 January 2021

Figures(12)

Herein, Fe species modified urchin-like Nb₂O₅ nanospheres were prepared by directly introducing Fe³⁺ cations into the system on the basis of synthesizing urchin-like Nb₂O₅ nanospheres via hydrothermal method. The synthesized samples were characterized in detail by power X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FT-IR), scanning electron microscopy(SEM), transmission electron microscopy(TEM), N₂ adsorption-desorption test, X-ray photoelectron spectroscopy(XPS), UV-Vis absorption spectroscopy(UV-Vis) and photoluminescence emission spectroscopy(PL). The results indicated that Fe³⁺ cations had no obvious effect on the morphology and hexagonal structure of Nb₂O₅, but could increase the specific surface area of samples. The Fe species of Fe₂O₃ and Fe(Ⅱ)Nb_xO_y with low crystallinity were most likely to be form in situ on the Nb₂O₅ surface during the experiment and uniformly dispersed. Compared with pure urchin-like Nb₂O₅ nanospheres, the Fe species modified Nb₂O₅ samples exhibited high photocatalytic activity under full light irradiation, and they could selectively degrade quasiphenothiazine dyes of methylene blue(MB) and toluidine blue(TB) with a high efficiency.One of the reasons is that Fe species can form coordination adsorption with N and S in quasi-phenothiazine dye molecules. Moreover, Fe species can separate photoexcited electrons of Nb₂O₅ and then decrease the recombination of photoexcited electron/hole by their matched conduction band(CB) with Nb₂O₅, and leading to the improvement of hole oxidation activity. Furthermore, Fenton reaction under the presence of trace H₂O₂ quickly consumes photoelectrons and generates a number of ·OH radicals to oxidize dye molecules.
- Nb₂O₅,
- surface chemistry,
- photocatalysis,
- phenothiazine dyes,
- Fenton reaction
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沈阳化工大学材料科学与工程学院沈阳 110142

Photocatalytic Degradation of Quasi-phenothiazine Dyes by Fe Species Modified Urchin-like Nb2O5 Nanospheres

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通讯作者: 陈斌, bchen63@163.com

Photocatalytic Degradation of Quasi-phenothiazine Dyes by Fe Species Modified Urchin-like Nb₂O₅ Nanospheres