Citation: Hua YANG, Yu-Ze WU, Hua-Li CUI, Lin LIU, Ji-Jiang WANG, Xiao-Li CHEN. Three-Dimensional Cd-MOF Based on Benzenetetracarboxilic Acid and Bis(imidazolylmethyl)benzene Ligands: Synthesis, Structure and Fluorescence Property[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 465-472. doi: 10.11862/CJIC.2021.051 shu

Three-Dimensional Cd-MOF Based on Benzenetetracarboxilic Acid and Bis(imidazolylmethyl)benzene Ligands: Synthesis, Structure and Fluorescence Property

Yan'an Laboratory of New Energy & New Function Materials, Shannxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: Hua YANG, yanghua_08@163.com
Received Date: 23 September 2020
Revised Date: 2 November 2020

Figures(13)

One new 3D metal-organic framework with formula[Cd(L)_0.5(1, 3-bib)(H₂O)]·H₂O (1) was prepared under hydrothermal conditions by employing the rigid 1, 2, 4, 5-benzenetetracarboxilic acid (H₄L) as the primary ligand and 1, 3-bis(1H-imidazole-1-ylmethyl)benzene(1, 3-bib) as the ancillary ligand. Complex 1 was characterized by elemental analysis, infrared spectroscopy, X-ray single crystal diffractometer, thermogravimetric analysis and X-ray powder diffractometer. The results show that complex 1 belongs to orthorhombic system, Pbca space group with cell parameters: a=0.857 08(4) nm, b=1.912 23(10) nm, c=2.451 60(12) nm. In complex 1, the carboxyl ligand L^4- chelates the metal centers via bidentate mode. The metal centers are coordinated by L^4- and 1, 3-bib to form a three-dimensional structure. The fluorescent properties of 1 were studied. Complex 1 shows strong luminescent peak at 454 nm. The luminescence of complex 1 can be quenched by acetone, MnO₄^- and Hg²⁺ ions, indicating that complex 1 was a good sensor for them. CCDC: 1966559.
- 1, 2, 4, 5-benzenetetracarboxilic acid,
- hydrothermal method,
- complex,
- fluorescence recognition
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