Citation: Jie-Wei LUO, Bo ZHAO, Shi-Lu ZHANG, Fei-Yun JIA, Jun LIU. Detection of Fe³⁺ and Cu²⁺ by Fluorescence Probe of Pyrazoline Derivatives with 9-Anthralaldehyde as Fluorescent Group[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 421-430. doi: 10.11862/CJIC.2021.048 shu

Detection of Fe³⁺ and Cu²⁺ by Fluorescence Probe of Pyrazoline Derivatives with 9-Anthralaldehyde as Fluorescent Group

Basic Medical School, North Sichuan Medical College, Nanchong, Sichuan 637000, China

Corresponding author: Jie-Wei LUO, luojiewei198021@163.com
Received Date: 2 May 2020
Revised Date: 18 December 2020

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A novel fluorescent sensor 1, 5-diphenyl-3-(10-(morpholinemethyl)anthracene-2-yl)pyrazoline (PMAP) was synthesized successfully, and characterized by ¹H NMR and ¹³C NMR spectracopy and X ray single crystal diffraction. Selective recognition of PMAP for cations was investigated by fluorescence emission spectrum and ultraviolet-visible absorption spectrum.The results showed that the PMAP exhibited high selective and sensitive to Fe³⁺ (for a ca. 45 nm red shift) and Cu²⁺, showing color change from pale yellow to blue and the fluorescence quantum yield decreased from 0.14 to 0.05 and 0.04, respectively. The sensor demonstrated a 1:1 binding stoichiometry to Fe³⁺/Cu²⁺ as well as a low detection limit of ca. 1 μmol·L^-1, and interference experiments revealed that this sensor had an excellent anti-interference ability. Furthermore, the sensor can be effectively applied for the detection of Cu²⁺ and Fe³⁺ in practical water samples. In addition, a three-input NOR logic gate circuit was constructed at the molecular level by the quantum yield of PMAP for Fe³⁺, Cu²⁺and H⁺ in different combinations. CCDC: 2051694.
- pyrazoline derivative,
- single crystal,
- iron ion,
- copper ion
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Detection of Fe3+ and Cu2+ by Fluorescence Probe of Pyrazoline Derivatives with 9-Anthralaldehyde as Fluorescent Group

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通讯作者: 陈斌, bchen63@163.com

Detection of Fe³⁺ and Cu²⁺ by Fluorescence Probe of Pyrazoline Derivatives with 9-Anthralaldehyde as Fluorescent Group