Citation: Xiao-Li CHEN, Lu SHANG, Meng-Ping HUANG, Yu-Qing TONG, Jia-nan ZHANG, Wan-Nian XUE. Two Complexes Based on Terpyridine/Benzotricarboxylic Acid Ligands: Synthesis, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 340-350. doi: 10.11862/CJIC.2021.037 shu

Two Complexes Based on Terpyridine/Benzotricarboxylic Acid Ligands: Synthesis, Structures and Properties

School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy & New Function Materials, Yanan University, Yan′an, Shaanxi 716000, China

Corresponding author: Xiao-Li CHEN, chenxiaoli003@163.com
Received Date: 20 May 2020
Revised Date: 2 November 2020

Figures(11)

A coordination polymer (CP) and a complex based on H₃tbtd/H₃bbta and bpy ligands, namely {[Co₃(tbtd)₂ (bpy)₂(H₂O)]·5H₂O}_n (1) and[Cd₂(Hbbta)(bpy)₃(C₂O₄)(H₂O)] (2) (H₃tbtd=4-(2, 4, 6-tricarboxylphenyl)-2, 2', 6', 2″-terpyridine, H₃bbta=1-fluoro-2, 4, 6-phenyltriacid, bpy=2, 2'-dipyridine), have been hydrothermal synthesized and structurally characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction analyses. 1 shows 2D network structure, which is linked into 3D supramolecular network through intermolecular hydrogen bonding interactions. 2 is binuclear structure, which is linked by π…π stack interactions and hydrogen bonding interactions to form 2D supramolecular network. CP 1 exhibited photocatalytic activities for degradation of methyl orange (MO) under UV light irradiation and showed good stabilities toward UV-light photocatalysis. In addition, luminescence property of 2 and thermal stabilities of 1~2 were also studied.CCDC: 1986403, 1, 2004223, 2.
- 4-(2, 4, 6-tricarboxylphenyl)-2, 2', 6', 2″-terpyridine,
- 1-fluoro-2, 4, 6-phenyltriacid,
- crystal structure,
- luminescence,
- photocatalysis
1. [1]
  Zhang Y, Yuan S, Day G, Wang X, Yang X Y, Zhou H C. Coord. Chem. Rev., 2018, 354:28-45
2. [2]
  Yang X G, Ma L F, Yan D P. Chem. Sci., 2019, 10:4567-4572 doi: 10.1039/C9SC00162J
3. [3]
  Yoon M, Srirambalaji R, Kim K. Chem. Rev., 2012, 112:1196-1231 doi: 10.1021/cr2003147
4. [4]
  Chen Y Z, Wang Z U, Wang H, Schlüter A D. J. Am. Chem. Soc., 2017, 139:2035-2039 doi: 10.1021/jacs.6b12074
5. [5]
  Qiu S L, Xue M, Zhu G S. Chem. Soc. Rev., 2014, 43:6116-6140 doi: 10.1039/C4CS00159A
6. [6]
  Han S D, Liu S J, Wang Q L, Mao X H, Hu T L, Bu X H. Cryst. Growth Des., 2015, 15:2253-2259 doi: 10.1021/acs.cgd.5b00024
7. [7]
  Ye Y, Du J F, Sun L B, Liu Y C, Wang S, Song X W, Liang Z Q. Dalton Trans., 2020, 49:1135-1142 doi: 10.1039/C9DT04305E
8. [8]
  Liu L, Wang S M, Han Z B. Inorg. Chem., 2016, 55:3558-3565 doi: 10.1021/acs.inorgchem.6b00050
9. [9]
  Chai D F, Gómez-García C J, Li B N, Pang H J, Ma H Y, Wang X M, Tan L C. Chem. Eng. J., 2019, 373:587-597
10. [10]
  Hou Y, Chai D F, Li B N, Pang H J, Ma H Y, Wang X M, Tan L C. ACS Appl. Mater. Interfaces, 2019, 11:20845-20853 doi: 10.1021/acsami.9b04649
11. [11]
  Zhao J, Wang Y N, Dong W, Wu Y, Li D S, Liu B, Zhang Q. Chem. Commun., 2015, 51:9479-9482 doi: 10.1039/C5CC02043C
12. [12]
  Li X Z, Li M A, Li Z, Shinkai S J. Angew. Chem. Int. Ed., 2008, 47:6371-6374 doi: 10.1002/anie.200801481
13. [13]
  Cunha D, Yahia M B, Hall S, Miller H. Chevreau H, Elkaim E, Maurin G, Horcajada P, Serre C. Chem. Mater., 2013, 25:2767-2776 doi: 10.1021/cm400798p
14. [14]
  Li D S, Wu Y P, Zhao J, Zhang J, Lu J Y. Coord. Chem. Rev., 2014, 261:1-27 doi: 10.1016/j.ccr.2013.11.004
15. [15]
  Zhao B, Cheng P, Chen X Y, Cheng C, Shi W, Liao D Z, Yan S P, Jiang Z H. J. Am. Chem. Soc., 2004, 126:3012-3013 doi: 10.1021/ja038784e
16. [16]
  Zeng M H, Feng X L, Chen X M. Dalton Trans., 2004:2217-2223
17. [17]
  Patra R, Titi H M, Goldberg I. CrystEngComm, 2013, 15:2853-2862
18. [18]
  Sun D, Han L L, Yuan S, Deng Y K; Xu M Z, Sun D F. Cryst. Growth Des., 2013, 13:377-385
19. [19]
  Wang X T, Li R Y, Liu A G, Yue C P, Wang S Min, Cheng J J, Li J P, Liu Z Y. J. Mol. Struct., 2019, 1184:503-511
20. [20]
  Sheldrick G M. Acta Crystallogr. Sect. C, 2015, C71:3-8
21. [21]
  ZHANG C J, Sukhen B, NI Z P, TONG M L. Chinese J. Inorg. Chem., 2019, 35(5):910-914
22. [22]
  Dong X Y, Si C D, Fan Y. Hu D C, Yao X Q, Yang Y X, Liu J C. Cryst. Growth Des., 2016, 16:2062-2073
23. [23]
  Cao Z, Wang J J, Tang L, Wang X, Hou X Y, Ju P, Ren Y X. Chin. J. Struct. Chem., 2018, 37:1771-1780
24. [24]
  Chen S, Fan R. Q, Sun C F, Wang P, Yang Y L, Su Q, Mu Y. Cryst. Growth Des., 2012, 12:1337-1346
25. [25]
  Xia J, Wang H S, Shi W, Ma Y, Song H, Cheng P, Liao D Z, Yan S P. Inorg. Chem., 2007, 46:3450-3458
26. [26]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 6th ed. New York:Wiley, 2009.
27. [27]
  Liu H Y, Liu B, Yang J, Liu Y, Ma J, Wu H. Dalton Trans., 2011, 40:9782-9788
28. [28]
  Zhang L Y, Liu G F, Zheng S L, Ye B H. Eur. J. Inorg. Chem., 2003:2965-2971
29. [29]
  Wang X L, Qin C, Wang E B, Xu L, Su Z M, Hu C W. Angew. Chem. Int. Ed., 2004, 43:5036-5040
30. [30]
  Peng Y F, Zhao S, Li K, Liu L, Li B L, Wu B. CrystEngComm, 2015, 17:2544-2552
31. [31]
  Liu G N, Li K, Fan Q S, Sun H, Li X Y, Han X N, Li Y, Zhang Z W, Li C C. Dalton Trans., 2016, 45:19062-19071
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