Citation: Zhou-Rong XIAO, Fang HOU, Xiang-Wen ZHANG, Li WANG, Guo-Zhu LI. Preparation of Ordered Mesoporous Nitrogen Doped Carbon Supported Fe₂O₃ for Oxygen Reduction Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(2): 243-250. doi: 10.11862/CJIC.2021.024 shu

Preparation of Ordered Mesoporous Nitrogen Doped Carbon Supported Fe₂O₃ for Oxygen Reduction Reaction

Zhou-Rong XIAO ¹ ,
Fang HOU ¹ ,
Xiang-Wen ZHANG ^{1, 2} ,
Li WANG ^{1, 2} ,
Guo-Zhu LI ^{1, 2,,}

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
2.
Collaborative Innovation Center of Chemical Science & Engineering, Tianjin University, Tianjin 300072, China

Corresponding author: Guo-Zhu LI, gzli@tju.edu.cn
Received Date: 30 July 2020
Revised Date: 27 October 2020

Figures(11)

Ordered mesoporous nitrogen doped carbon supported iron oxide was prepared, which effectively reduced the overpotential of oxygen reduction. The physicochemical properties of the as-prepared catalysts were characterized by scanning electron microscopy, transmission electron microscopy, nitrogen adsorption-desorption test, powder X-ray diffraction, X-ray photoelectron spectroscopy and Raman spectroscopy. In addition, the activity and selectivity for oxygen reduction reaction was tested by rotating disc electrode under alkaline conditions. The results show that iron was loaded in ordered mesoporous nitrogen doped carbon in the form of Fe₂O₃ after nitrogen pyrolysis, and its specific surface area reached 755 cm²·g^-1. The results of Raman and X-ray photoelectron spectroscopy show that the graphitization degree of the catalyst increased with adding iron precursor. The impedance was decreased and its conductivity was increased. Under alkaline conditions, Fe₂O₃@NC exhibited a 4-electron oxygen reduction reaction, and its initial potential (-0.01 V vs Ag/AgCl) and half slope potential (-0.13 V vs Ag/AgCl) were comparable to those of commercial 20% Pt/C. In addition, the catalyst had superior methanol resistance and excellent constant voltage stability compared with commercial Pt/C. The discharge power of Fe₂O₃@NC reached 88 mW·cm^-2, which was 1.29 times that of commercial Pt/C.
- oxygen reduction reaction,
- fuel cell,
- Fe₂O₃,
- nitrogen doped carbon,
- mesoporous
1. [1]
  Peng X W, Zhang L, Chen Z X, Zhong L X, Zhao D K, Chi X, Zhao X X, Li L G, Lu X H, Leng K, Liu C B, Liu W, Tang W, Loh K P. Adv Mater., 2019, 31:1900341-1900347
2. [2]
  Gewirth A A, Varnell J A, DiAscro A M. Chem. Rev., 2018, 118:2313-2339 doi: 10.1021/acs.chemrev.7b00335
3. [3]
  Zhu C Z, Li H, Fu S F, Du D, Lin Y H. Chem. Soc. Rev., 2016, 45:517-531 doi: 10.1039/C5CS00670H
4. [4]
  Gao W B, Zhang Z P, Dou M L, Wang F. ACS Catal., 2019, 9:3278-3288
5. [5]
  Xiao Z R, Hou F, Li Y T, Zhang R R, Shen G Q, Wang L, Zhang X W, Wang Q F, Li G Z. Chem. Eng. Sci., 2019, 207:235-246
6. [6]
  Liu S, Li G Z, Gao Y Y, Xiao Z R, Zhang J F, Wang Q F, Zhang X W, Wang L. Catal. Sci. Technol., 2017, 7:4007-4016
7. [7]
  Hu E L, Yu X Y, Chen F, Wu Y D, Hu Y, Lou X W. Adv. Energy Mater., 2018, 8:1702476-1702483
8. [8]
  Zang Y P, Zhang H M, Zhang X, Liu R R, Liu S W, Wang G Z, Zhang Y X, Zhao H J. Nano Res., 2016, 9:2123-2137
9. [9]
  Tian Y H, Xu L, Qian J C, Bao J, Yan C, Li H N, Li H M, Zhang S Q. Carbon, 2019, 146:763-771
10. [10]
  Gao Y Y, Wang L, Li G Z, Xiao Z R, Wang Q F, Zhang X W. Int. J. Hydrogen Energy, 2018, 43:7893-7902
11. [11]
  Xiao Z R, Hou F, Zhang R R, Li Y T, Yuan G, Pan L, Zou J J, Wang L, Zhang X W, Li G Z. Catal. Sci. Technol., 2019, 9:4581-4587
12. [12]
  Gao S Y, Fan B F, Feng R, Ye C L, Wei X J, Liu J, Bu X H. Nano Energy, 2017, 40:462-470
13. [13]
  Wang H T, Wang W, Gui M X, Muhammad A, Wang Z Y, Yu Y, Xiao J W, Liu H F. ACS Appl. Mater. Interfaces, 2017, 9:335-344
14. [14]
  Wang H T, Wang W, Xu Y Y, Dong S, Xiao J W, Wang F, Liu H F, Xia B Y. ACS Appl. Mater. Interfaces, 2017, 9(12):10610-10617 doi: 10.1021/acsami.6b15392
15. [15]
  He J N, Li B B, Mao J, Liang Y Q, Yang X J, Cui Z D, Zhu S L, Li Z Y. J. Mater. Sci., 2017, 52:10938-10947
16. [16]
  Dhavale V, Singh S, Nadeema A, Gaikwad S, Kurungot S. Nanoscale, 2015, 7:20117-20125 doi: 10.1039/C7NR90179H
17. [17]
  Li B, Chen Y, Ge X M, Chai J W, Zhang X, Andy Hor T S, Du G J, Liu Z L, Zhang H, Zong Y. Nanoscale, 2016, 8:5067-5075
18. [18]
  Guo D K, Han S C, Wang J C, Zhu Y F. Appl. Surf. Sci., 2018, 434:1266-1273
19. [19]
  Ao X, Zhang W, Li Z S, Li J G, Soule L, Huang X, Chiang W H, Chen H M, Wang C D, Liu M L, Zeng X C. ACS Nano, 2019, 13(10):11853-11862
20. [20]
  Li Y Q, Huang H Y, Chen S R, Yu X, Wang C, Ma T L. Nano Res., 2019, 12(8):1900-1905
1. [1]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
2. [2]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
3. [3]
  Shiqi Zhang , Heng Zhang , Aiwen Lei . 从物理化学的角度看化学能的利用. University Chemistry, 2025, 40(6): 310-315. doi: 10.12461/PKU.DXHX202408124
4. [4]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
5. [5]
  Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V₂O₃@Pourous Carbon Nanosheets Derived from V₂CF_x MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020
6. [6]
  Yachao HUANG , Chuanwang ZENG , Guiyong LIU , Jinming ZENG , Chao LIU , Xiaopeng QI . Oxygen vacancies and phosphorus doping enhanced metal-organic framework derived nitrogen-doped carbon-coated Co₃O₄ bifunctional electrocatalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2251-2260. doi: 10.11862/CJIC.20250133
7. [7]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
8. [8]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
9. [9]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
10. [10]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
11. [11]
  Shiqian WEI , Xinyu TIAN , Hong LIU , Maoxia CHEN , Fan TANG , Qiang FAN , Weifeng FAN , Yu HU . Oxygen reduction reaction/oxygen evolution reaction catalytic performances of different active sites on nitrogen-doped graphene loaded with iron single atoms. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1776-1788. doi: 10.11862/CJIC.20250102
12. [12]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
13. [13]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
14. [14]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . Insights into the greatly improved catalytic performance of N-doped BiOBr for CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-0. doi: 10.1016/j.actphy.2025.100055
15. [15]
  Haotong Ma , Mingyu Heng , Yang Xu , Wei Bi , Yingchun Miao , Shuning Xiao . Synergistic carbon doping and Cu loading on boron nitride via microwave synthesis for enhanced atmospheric CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(11): 100132-0. doi: 10.1016/j.actphy.2025.100132
16. [16]
  Fangfang WANG , Jiaqi CHEN , Weiyin SUN . CuBi@Cu-MOF composite catalysts for electrocatalytic CO₂ reduction to HCOOH. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 97-104. doi: 10.11862/CJIC.20240350
17. [17]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . Defective Ultrathin Two-Dimensional Materials for Photo-/Electrocatalytic CO₂ Reduction: Fundamentals and Perspectives. Acta Physico-Chimica Sinica, 2025, 41(3): 100019-0. doi: 10.3866/PKU.WHXB202308052
18. [18]
  Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
19. [19]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
20. [20]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(3750)
HTML views(725)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ordered Mesoporous Nitrogen Doped Carbon Supported Fe2O3 for Oxygen Reduction Reaction

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Ordered Mesoporous Nitrogen Doped Carbon Supported Fe₂O₃ for Oxygen Reduction Reaction