Citation: XU Jun-Ge, HONG Jun-Xian, HU Die. Composite Catalyst α-(Fe, Cu)OOH/RGO: Synthesis, Characterization and Removal of Ciprofloxacin Synergized with H₂O₂ under Visible Light[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 55-64. doi: 10.11862/CJIC.2021.008 shu

Composite Catalyst α-(Fe, Cu)OOH/RGO: Synthesis, Characterization and Removal of Ciprofloxacin Synergized with H₂O₂ under Visible Light

College of Civil Engineering, Fuzhou University, Fuzhou 350116, China

Corresponding author: XU Jun-Ge, xujunge@163.com
Received Date: 15 June 2020
Revised Date: 17 September 2020

Figures(14)

The composite α-(Fe, Cu)OOH/RGO was synthesized via one-step reflux method. The as-obtained catalyst was analyzed by means of X-ray powder diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and other characterization methods. With 30 mg·L^-1 ciprofloxacin (CIP) as the target pollutant, the effect of the catalyst obtained under different synthesis conditions on the removal of CIP by H₂O₂ under visible light was investigated. The results show that α-(Fe, Cu)OOH nanorods were grown in situ on two-dimensional graphene sheets. The visible light absorption edge of α-(Fe, Cu)OOH/RGO composite material was red-shifted and the band gap was changed from 2.02 to 1.76 eV. Graphene composite could not only enhance the adsorption capacity of pollutants, but also accelerate the separation and transfer rate of photogenerated electrons, as well as improve the efficiency of electron conduction in the reaction system. The best catalytic performance was gained when the composite content (mass fraction) of graphene was 1%. The CIP was completely removed after 120 min when the addition of catalyst was 0.40 g·L^-1 and the concentration of H₂O₂ was 0.10 mol·L^-1. The removal efficiency of CIP reached to 90% even after fivetime reuse, which indicates that the catalyst has strong catalytic activity and good stability.
- α-(Fe, Cu)OOH/RGO,
- graphene composite,
- photo-Fenton reaction,
- ciprofloxacin
1. [1]
  Mirzazadeh H, Lashanizadegan M. J. Serb. Chem. Soc., 2018, 83(2):221-236
2. [2]
  Zhou Q X, Wang M G, Tong Y Y, Wang H Y, Zhou X Q, Sheng X Y, Sun Y, Chen C M. Ecotoxicol. Environ. Saf., 2019, 182:109472 doi: 10.1016/j.ecoenv.2019.109472
3. [3]
  Saroyan H, Ntagiou D, Samanidou V, Deliyanni E. Chemosphere, 2019, 225:524-534 doi: 10.1016/j.chemosphere.2019.02.200
4. [4]
  Nawaz M, Moztahida M, Kim J, Shahzad A, Jang J, Miran W, Lee D S. Carbohydr. Polym., 2018, 199:109-118 doi: 10.1016/j.carbpol.2018.07.007
5. [5]
  Saroyan H, Ntagiou D, Rekos K, Deliyanni E. Appl. Sci.-Basel, 2019, 9(10):2167 doi: 10.3390/app9102167
6. [6]
  Israr M, Iqbal J, Arshad A, Aisida S O, Ahmad I. J. Phys. Chem. Solids, 2020, 140:109333 doi: 10.1016/j.jpcs.2020.109333
7. [7]
  Suwanchawalit C, Somjit V. Dig. J. Nanomater. Biostruct., 2015, 10(3):769-777
8. [8]
  Xu J G, Li Y Q, Yuan B L, Shen C H, Fu M L, Cui H J, Sun W J. Chem. Eng. J., 2016, 291:174-183 doi: 10.1016/j.cej.2016.01.059
9. [9]
  Krehula S, Ristić M, Petrović Ž, Mitar I, Musić S. J. Alloys Compd., 2019, 802:290-300 doi: 10.1016/j.jallcom.2019.06.133
10. [10]
  Nishida N, Amagasa S, Kobayashi Y, Yamada Y. J. Nanopart. Res., 2018, 20(7):181 doi: 10.1007/s11051-018-4275-6
11. [11]
  Kim J H, Kaneko H, Minegishi T, Kubota J, Domen K, Lee J S. ChemSusChem, 2016, 9(1):61-66 doi: 10.1002/cssc.201501401
12. [12]
  Wang Y, TianN H L, Yu Y G, Hu C Z. Chemosphere, 2018, 208:931-941 doi: 10.1016/j.chemosphere.2018.06.007
13. [13]
  Zhang Y X, Cheng Y X, Chen N N, Zhou Y Y, Li B Y, Gu W, Shi X H, Xian Y Z. J. Colloid Interface Sci., 2014, 421:85-92 doi: 10.1016/j.jcis.2014.01.022
14. [14]
  Zubir N A, Zhang X W, Yacou C, Da Costa J C D. Sci. Adv. Mater., 2014, 6(7):1382-1388 doi: 10.1166/sam.2014.1812
15. [15]
  Chong S, Zhang G M, Liu Y C, Zhang N, Huang G T, Wang H C. Desalin. Water Treat., 2017, 84:255-261 doi: 10.5004/dwt.2017.21192
16. [16]
  Feng Y, Yao T J, Yang Y, Zheng F R, Chen P, Wu J, Xin B F. ChemistrySelect, 2018, 3(31):9062-9070 doi: 10.1002/slct.201801840
17. [17]
  WANG Y Y, ZHAO H Y, HOU Z Y. Chem. J. Chinese Universities, 2018, 39(8):1750-1758
18. [18]
  Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958, 80(6):1339 doi: 10.1021/ja01539a017
19. [19]
  Fu D D, He Z Q, Su S S, Xu B, Liu Y L, Zhao Y P. J. Colloid Interface Sci., 2017, 505:105-114 doi: 10.1016/j.jcis.2017.05.091
20. [20]
  Tian J J, Na W, Wang H, Gao W G. J. Cent. South Univ., 2014, 21(2):482-486 doi: 10.1007/s11771-014-1964-x
21. [21]
  Krehula S, Krehula L K, Musić S. J. Alloys Compd., 2013, 581:335-343 doi: 10.1016/j.jallcom.2013.07.076
22. [22]
  Andjelkovic I, Tran D N H, Kabiri S, Azari S, Markovic M, Losic D. ACS Appl. Mater. Interfaces, 2015, 7(18):9758-9766 doi: 10.1021/acsami.5b01624
23. [23]
  Pradhan G K, Padhi D K, Parida K M. ACS Appl. Mater. Interfaces, 2013, 5(18):9101-9110 doi: 10.1021/am402487h
24. [24]
  Padhi D K, Parida K. J. Mater. Chem. A, 2014, 2(26):10300-10312 doi: 10.1039/C4TA00931B
25. [25]
  Xu T, Hu J, Yang Y, Que W X, Yin X T, Wu H J, Chen L X. J. Mater. Sci. Mater. Electron., 2018, 29(6):4888-4894 doi: 10.1007/s10854-017-8447-4
26. [26]
  Nie Y L, Hu C, Qu J H, Zhao X. Appl. Catal. B, 2009, 87(1/2):30-36
27. [27]
  Zhang R, You H, Wu D H. Desalin. Water Treat., 2016, 57(26):12010-12018 doi: 10.1080/19443994.2015.1048535
28. [28]
  Yang Y, Ratner M A, Schatz G C. J. Phys. Chem. C, 2014, 118(50):29196-29208 doi: 10.1021/jp5052672
29. [29]
  YAO Z P, CHEN C J, WAGN J K, XIA Q X, LI C X, JIANG Z H. Chinese J. Inorg. Chem., 2017, 33(10):1797-1804 doi: 10.11862/CJIC.2017.197
30. [30]
  Zhang X F, Zhang B Y, Liu S S, Kang H W, Kong W Q, Zhang S R, Shen Y, Yang B C. Appl. Surf. Sci., 2018, 436:974-980 doi: 10.1016/j.apsusc.2017.12.078
31. [31]
  Kuang L Y, Liu Y Y, Fu D D, Zhao Y P. J. Colloid Interface Sci., 2017, 490:259-269 doi: 10.1016/j.jcis.2016.11.071
32. [32]
  Han S C, Hu L F, Liang Z Q, Wageh S, Al-Ghamdi A A, Chen Y S, Fang X S. Adv. Funct. Mater., 2014, 24(36):5719-5727 doi: 10.1002/adfm.201401279
33. [33]
  Wang Y, Tian H L, Yu Y G, Hu C Z. Chemosphere, 2018, 208:931-941 doi: 10.1016/j.chemosphere.2018.06.007
34. [34]
  Zhang W, Hu C, Tan J, Fan Z J, Chi F L, Sun Y X, Ran S L, Liu X G, Lv Y H. NANO, 2016, 11(6):109-117
35. [35]
  Lin F J, Yuan M, Chen Y, Huang Y P, Lian J B, Qiu J X, Xu H, Li H M, Yuan S Q, Zhao Y, Cao S S. Electrochim. Acta, 2019, 320:UNSP 134580 doi: 10.1016/j.electacta.2019.134580
36. [36]
  Peng F M, Luo T, Qiu L G, Yuan Y P. Mater. Res. Bull., 2013, 48(6):2180-2185 doi: 10.1016/j.materresbull.2013.02.056
37. [37]
  Zhang X X, Li R P, Jia M K, Wang S L, Huang Y P, Chen C C. Chem. Eng. J., 2015, 274:290-297 doi: 10.1016/j.cej.2015.03.077
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Composite Catalyst α-(Fe, Cu)OOH/RGO: Synthesis, Characterization and Removal of Ciprofloxacin Synergized with H2O2 under Visible Light

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通讯作者: 陈斌, bchen63@163.com

Composite Catalyst α-(Fe, Cu)OOH/RGO: Synthesis, Characterization and Removal of Ciprofloxacin Synergized with H₂O₂ under Visible Light