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Citation: CHAO Ming-Kun, MA Gui-Jun. Flux-Assisted Preparation of Sm2Ti2S2O5 Powder Applied to Photocatalytic H2 Production from Water[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 16-22. doi: 10.11862/CJIC.2021.006 shu

Flux-Assisted Preparation of Sm2Ti2S2O5 Powder Applied to Photocatalytic H2 Production from Water

  • 1.

    School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

  • 2.

    Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China

  • 3.

    University of Chinese Academy of Sciences, Beijing 100049, China

  • Corresponding author: MA Gui-Jun, magj@shanghaitech.edu.cn
  • Received Date: 16 June 2020
    Revised Date: 11 September 2020

Figures(9)

  • Sm2Ti2S2O5 (STSO) was prepared by a flux method using TiO2, TiS2 and Sm2O3 as reactants, and eutectic of LiCl and KCl (LiCl-KCl) or LiCl and CsCl (LiCl-CsCl) as flux. By analyzing X-ray diffraction patterns of the samples synthesized at different temperatures, it was firstly demonstrated that the threshold crystallization temperature of STSO was 520℃, much lower than the value of 650℃ that was reported previously as the lowest temperature for synthesizing STSO. Scanning electron microscope images showed that the synthesized STSO particles owned a platelike morphology. At the same temperature, LiCl-CsCl led to lower plate thickness than LiCl-KCl. The average photocatalytic H2 production rate showed volcano-like profile to synthesizing temperature, which was likely due to the effect of particle size and crystallinity on activity. Variation of hole sacrificial reagent showed that ascorbic acid produced much higher H2 evolution activity than Na2S-Na2SO3, triethylamine, triethanolamine and methanol. For the purpose of comparing with the literatures, Na2S-Na2SO3 was employed as sacrificial reagent in the following stability test. It was found that the as-prepared STSO exhibited stable H2 production over 20 h under visible light (Xe lamp, λ>420 nm) irradiation, and having nearly identical characterization results in XPS, XRD and TEM before and after photocatalytic reaction.
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    1. [1]

      Kudo A, Miseki K. Chem. Soc. Rev., 2009, 38(1):253-278
       

    2. [2]

      Takata T, Domen K. Dalton Trans., 2017, 46(32):10529-10544  doi: 10.1039/C7DT00867H

    3. [3]

      Michael G W, Emily L W, James R M, Shannon W B, Mi Q X, Eliza-beth A S, Nathan S L. Chem. Rev., 2010, 110:6446-6473  doi: 10.1021/cr1002326

    4. [4]

      Suzuki T, Hisatomi T, Teramura K, Shimodaira Y, Kobayashi H, Domen K. Phys. Chem. Chem. Phys., 2012, 14(44):15475-15481  doi: 10.1039/c2cp43132g

    5. [5]

      Ma G J, Suzuki Y, Singh R B, Iwanaga A, Moriya Y, Minegishi T, Liu J, Hisatomi T, Nishiyama H, Katayama M, Seki K, Furube A, Yama-da T, Domen K. Energy Environ. Sci., 2014, 7(7):2239-2242  doi: 10.1039/C4EE00091A

    6. [6]

      Ma G J, Suzuki Y, Singh R B, Iwanaga A, Moriya Y, Minegishi T, Liu J, Hisatomi T, Nishiyama H, Katayama M, Seki K, Furube A, Yama-da T, Domen K. Chem. Sci., 2015, 6(8):4513-4518  doi: 10.1039/C5SC01344E

    7. [7]

      Hisatomi T, Okamura S, Liu J Y, Shinohara Y, Ueda K, Higashi T, Katayama M, Minegishi T, Domen K. Energy Environ. Sci., 2015, 8(11):3354-3362  doi: 10.1039/C5EE02431E

    8. [8]

      Song Z M, Hisatomi T, Chen S S, Wang Q, Ma G, Li S, Zhu X, Sun S, Domen K. ChemSusChem, 2019, 12(9):1906-1910  doi: 10.1002/cssc.201802306

    9. [9]

      Wang Q, Nakabayashi M, Hisatomi T, Sun S, Akiyama S, Wang Z, Pan Z, Xiao X, Watanabe T, Yamada T, Shibata N, Takata T, Domen K. Nat. Mater., 2019, 18(8):827-832  doi: 10.1038/s41563-019-0399-z

    10. [10]

      Goto Y, Seo J, Kumamoto K, Hisatomi T, Mizuguchi Y, Kamihara Y, Katayama M, Minegishi T, Domen K. Inorg. Chem., 2016, 55(7):3674-3679  doi: 10.1021/acs.inorgchem.6b00247

    11. [11]

      Ishikawa A, Takata T, Junko N, Hara M, Kobayashi H, Domen K. J. Am. Chem. Soc., 2002, 124(45):13547-13553  doi: 10.1021/ja0269643

    12. [12]

      Ma G J, Chen S S, Kuang Y B, Akiyama S, Hisatomi T, Nakabayashi M, Shibata N, Katayama M, Minegishi T, Domen K. J. Phys. Chem. Lett., 2016, 7(19):3892-3896  doi: 10.1021/acs.jpclett.6b01802

    13. [13]

      Zhao W, Maeda K, Zhang F X, Hisatomi T, Domen K. Phys. Chem. Chem. Phys., 2014, 16(24):12051-12056  doi: 10.1039/c3cp54668c

    14. [14]

      Ishikawa A, Yamada Y, Ishikawa A, Kondo J N, Hara M, Kobayashi H, Domen K. Chem. Mater., 2003, 15(23):4442-4446  doi: 10.1021/cm034540h

    15. [15]

      Ishikawa A, Takata T, Matsumura T, Kondo J N, Hara M, Kobayashi H, Domen K. J. Phys. Chem. B, 2004, 35(19):2637-2642
       

    16. [16]

      Li R G, Chen Z, Zhao W, Zhang F X, Maeda K, Huang B K, Shen S, Domen K, Li C. J. Phys. Chem. C, 2012, 117(1):376-382

    17. [17]

      Zhang F X, Maeda K, Takata T, Domen K. J. Catal., 2011, 280(1):1-7
       

    18. [18]

      Zhang F X, Maeda K, Takata T, Domen K. Catal. Today, 2012, 185(1):253-258

    19. [19]

      Zhang F X, Maeda K, Takata T, Domen K. Chem. Commun., 2010, 46(39):7313-7315  doi: 10.1039/c0cc02425b

    20. [20]

      Ma G J, Kuang Y B, Murthy D H K, Hisatomi T, Seo J, Chen S S, Matsuzaki H, Suzuki Y, Katayama M, Minegishi T, Seki K, Furube A, Domen K. J. Phys. Chem. C, 2018, 122(25):13492-13499  doi: 10.1021/acs.jpcc.7b12087

    21. [21]

      Kang Z Y, He M G, Lu G X, Zhang Y. Calphad, 2016, 55:208-218  doi: 10.1016/j.calphad.2016.09.005

    22. [22]

      Basin A S, Kaplun A B, Meshalkin A B, Uvarov N F. Russ. J. Inorg. Chem., 2008, 53(9):1509-1511

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