Citation: LIU De-Zheng, YANG Gao-Yuan, XIANG Wen-Hao, WANG Song, LI Wang-Nan, ZHONG Jie, HUANG Fu-Zhi, CHEN Mei-Hua, LIANG Gui-Jie. Perovskite Solar Cells Based on 1D/0D Ordered Composite SnO₂ Nanocrystal[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(1): 85-94. doi: 10.11862/CJIC.2021.005 shu

Perovskite Solar Cells Based on 1D/0D Ordered Composite SnO₂ Nanocrystal

1.
Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei University of Arts and Science, Xiangyang, Hubei 441053, China
2.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

Corresponding author: CHEN Mei-Hua, yunluo886@163.com LIANG Gui-Jie, guijie-liang@hotmail.com
Received Date: 12 July 2020
Revised Date: 16 September 2020

Figures(8)

Novel 1D/0D ordered composite SnO₂ nanocrystal electron transport layer (ETL) for pervoskite solar cells has been prepared by adjusting the density of one-dimensional (1D) nanorod arrays through adding functional additives in hydrothermal precursors, followed by depositing zero-dimensional (0D) nanoparticles between the nanorods. The effect of the NaCl additives in the precursor and the subsequent deposition of nanoparticles on the morphology, optical and interfacial charge transfer properties of the composite ETL was systematically studied, and the mechanism of the above effects on the photovoltaic performance of the device was discussed. The results show that the addition of NaCl in the precursor thins the rods' density, so that the following 0D nanoparticles penetrated smoothly into the gaps of 1D nanorods, inducing the obvious inhibitory effect on the perovskite/ETL and perovskite/FTO interface charge recombination, which is the direct reason for the increase in open circuit voltage and fill factor of the device. In summary, the excellent charge recombination inhibition (composite resistance was 2.9 times that of conventional 1D nanorod arrays ETL-2Cl) and efficient electron extraction performance (extraction rate and efficiency were 3.03×10⁷ s^-1 and 91.6%, respectively) of the novel 1D/0D ordered composite ETL-2P contributed to the better photoelectric performance of the device (with photoelectric efficiency of 12.15%).
- composite SnO₂ nanocrystals,
- morphology control,
- nanostructures,
- electron transport,
- perovskite solar cells
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Perovskite Solar Cells Based on 1D/0D Ordered Composite SnO2 Nanocrystal

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通讯作者: 陈斌, bchen63@163.com

Perovskite Solar Cells Based on 1D/0D Ordered Composite SnO₂ Nanocrystal