Citation: ZHANG Ke, WANG Hui-Sheng, YU Ling-Yan, CHEN Yong, PAN Zhi-Quan. Research Progress and Prospect on the First Series Transition Metal-Dy Single Molecule Magnets[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2205-2226. doi: 10.11862/CJIC.2020.264 shu

Research Progress and Prospect on the First Series Transition Metal-Dy Single Molecule Magnets

School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China

Corresponding author: WANG Hui-Sheng, wangch198201@163.com
Received Date: 28 June 2020
Revised Date: 2 October 2020

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Among the first series transition metal (TM) ions, not only the paramagnetic TM ions (such as Cr^Ⅲ, Mn^Ⅱ/ Mn^Ⅲ, Fe^Ⅱ/Fe^Ⅲ, Co^Ⅱ, Ni^Ⅱ and Cu^Ⅱ) but also diamagnetic TM ions (such as Co^Ⅲ and Zn^Ⅱ) can assemble with Dy^Ⅲ to form the TM-Dy single molecule magnets (TM-Dy SMMs). In this paper, we survey most of the TM-Dy complexes with SMM behavior. For the TM-Dy SMMs, two interesting phenomena should be emphasized on. One is some Cr-Dy complexes possessing relatively high blocking temperature (T_B) and large coercivities, which could be ascribed to the strong magnetic couplings between Cr^Ⅲ and Dy^Ⅲ ions (|J|>10 cm^-1). Another is the Fe^Ⅱ₂-Dy complex with the energy barrier of 319 cm^-1 (459 K), which is high among the TM-Dy SMMs. The reason might be that the axial symmetry of the coordination of Dy^Ⅲ ion is high (D_5h). Additionally, ab initio calculations indicate the excited state also possess high axial symmetry. Besides the Cr^Ⅲ-Dy and Fe^Ⅱ₂-Dy complexes, other TM-Dy SMMs usually exhibits relatively low energy barriers, which may be due to the weak magnetic interactions between paramagnetic TM ions and Dy^Ⅲ ions. To elimate the effect of the weak magnetic couplings on the relaxation behavior, the study of the DTM-Dy SMMs (DTM=diamagnetic the first series transition metal ions such as Co^Ⅲ and Zn^Ⅱ) has been received wide attention and their number is dramatically increasing. For the Zn-Dy SMMs, the number of the Zn₂Dy trinuclear complexes is larger than that of other Zn-Dy complexes, indicating that the Zn₂Dy received more attention. The reason might be that the coordination geometry of the Dy^Ⅲ in the Zn₂Dy complexes can be more easily modulated. Finally, we provided some reseach thoughts for further improving the SMM performance of the TM-Dy complexes; the most important thoughts are that the axial symmetry of the coordination geometries of Dy^Ⅲ ions and the distribution of charge density of Dy^Ⅲ ions in TM-Dy complexes should be controlled. For Dy^Ⅲ in the TM-Dy complexes, the electrostatic repulsion between the Dy^Ⅲ ground-m_J charge density and the ligand charge density should be minimized.
- single molecule magnets,
- the first series transition metal-Dy single molecule magnets,
- coordination geometries,
- easy magnetization axes,
- magnetic couplings
1. [1]
  Pan Y Z, Hua Q Y, Lin L S, et al. Inorg. Chem. Front., 2020, 7(12):2335-2342 doi: 10.1039/D0QI00326C
2. [2]
  Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993, 115(5):1804-1816 doi: 10.1021/ja00058a027
3. [3]
  Lin P H, Burchell T J, Clerac R, et al. Angew. Chem. Int. Ed., 2008, 47(46):8848-8851 doi: 10.1002/anie.200802966
4. [4]
  Wang H S, Long Q Q, Hu Z B, et al. Dalton Trans., 2019, 48(35):13472-13482 doi: 10.1039/C9DT02638J
5. [5]
  WANG Hui-Sheng, YUE Lin, PAN Min, et al. Chinese J. Inorg. Chem., 2016, 32(1): 153-160
6. [6]
  Wang H S, Song Y. Inorg. Chem. Commun., 2013, 35:86-88 doi: 10.1016/j.inoche.2013.05.016
7. [7]
  Murugesu M, Habrych M, Wernsdorfer W, et al. J. Am. Chem. Soc., 2004, 126(15):4766-4767 doi: 10.1021/ja0316824
8. [8]
  Stamatatos T C, Abboud K A, Wernsdorfer W, et al. Angew. Chem. Int. Ed., 2007, 46(6):902-906
9. [9]
  Tasiopoulos A J, Vinslava A, Wernsdorfer W, et al. Angew. Chem. Int. Ed., 2004, 43(16):2117-2121 doi: 10.1002/anie.200353352
10. [10]
  Abbasi P, Quinn K, Alexandropoulos D I, et al. J. Am. Chem. Soc., 2017, 139(44):15644-15647 doi: 10.1021/jacs.7b10130
11. [11]
  Stamatatos T C, Abboud K A, Wernsdorfer W, et al. Angew. Chem. Int. Ed., 2006, 45(25):4134-4137 doi: 10.1002/anie.200600691
12. [12]
  Ako A M, Hewitt I J, Mereacre V, et al. Angew. Chem. Int. Ed., 2006, 118(30):5048-5051 doi: 10.1002/ange.200601467
13. [13]
  Milios C J, Vinslava A, Wernsdorfer W, et al. J. Am. Chem. Soc., 2007, 129(10):2754-2755 doi: 10.1021/ja068961m
14. [14]
  Waldmann O. Inorg. Chem., 2007, 46(24):10035-10037 doi: 10.1021/ic701365t
15. [15]
  Ruiz E, Cirera J, Cano J, et al. Chem. Commun., 2008(1):52-54 doi: 10.1039/B714715E
16. [16]
  Neese F, Pantazis D A. Faraday Discuss., 2011, 148:229-238 doi: 10.1039/C005256F
17. [17]
  Kido T, Ikuta Y, Sunatsuki Y, et al. Inorg. Chem., 2003, 42(2):398-408 doi: 10.1021/ic026045d
18. [18]
  Guo F S, Day B M, Chen Y C, et al. Science, 2018, 362(6421):1400-1403 doi: 10.1126/science.aav0652
19. [19]
  Rinck J, Novitchi G, Van den Heuvel W, et al. Angew. Chem. Int. Ed., 2010, 49(41):7583-7587 doi: 10.1002/anie.201002690
20. [20]
  Langley S K, Forsyth C M, Moubaraki B, et al. Dalton Trans., 2015, 44(3):912-915 doi: 10.1039/C4DT03100H
21. [21]
  Thuesen C A, Pedersen K S, Schau-Magnussen M, et al. Dalton Trans., 2012, 41(37):11284-11292 doi: 10.1039/c2dt31302b
22. [22]
  Langley S K, Wielechowski D P, Vieru V, et al. Angew. Chem. Int. Ed., 2013, 52(46):12014-12019 doi: 10.1002/anie.201306329
23. [23]
  Langley S K, Le C, Ungur L, et al. Inorg. Chem., 2015, 54(7):3631-3642 doi: 10.1021/acs.inorgchem.5b00219
24. [24]
  Langley S K, Wielechowski D P, Moubaraki B, et al. Chem. Commun., 2016, 52(73):10976-10979 doi: 10.1039/C6CC06152D
25. [25]
  Xiang H, Lu W G, Zhang W X, et al. Dalton Trans., 2013, 42(4):867-870 doi: 10.1039/C2DT32651E
26. [26]
  Car P E, Favre A, Caneschi A, et al. Dalton Trans., 2015, 44(36):15769-15773 doi: 10.1039/C5DT02459E
27. [27]
  Vignesh K R, Soncini A, Langley S K, et al. Nat. Commun., 2017, 8:1023 doi: 10.1038/s41467-017-01102-5
28. [28]
  Chen S H, Mereacre V, Zhao Z Y, et al. Dalton Trans., 2018, 47(22):7456-7462 doi: 10.1039/C8DT01289J
29. [29]
  Ako A M, Mereacre V, Clerac R, et al. Chem. Commun., 2009(5):544-546 doi: 10.1039/B814614D
30. [30]
  Li X L, Min F Y, Wang C, et al. Dalton Trans., 2015, 44(7):3430-3438 doi: 10.1039/C4DT03713H
31. [31]
  Lin P H, Tsui E Y, Habib F, et al. Inorg. Chem., 2016, 55(12):6095-6099 doi: 10.1021/acs.inorgchem.6b00630
32. [32]
  Wang H S, Yang F J, Long Q Q, et al. Dalton Trans., 2016, 45(45):18221-18228 doi: 10.1039/C6DT02945K
33. [33]
  Akhtar M N, Lan Y, Aldamen M A, et al. Dalton Trans., 2018, 47(10):3485-3495 doi: 10.1039/C7DT04304J
34. [34]
  Vignesh K R, Langley S K, Moubaraki B, et al. Inorg. Chem., 2018, 57(3):1158-1170 doi: 10.1021/acs.inorgchem.7b02608
35. [35]
  Li M Y, Lan Y H, Ako A M, et al. Inorg. Chem., 2010, 49(24):11587-11594 doi: 10.1021/ic101754g
36. [36]
  Vignesh K R, Langley S K, Moubaraki B, et al. Chem. Eur. J., 2015, 21(46):16364-16369 doi: 10.1002/chem.201503424
37. [37]
  Schmidt S F M, Merkel M P, Kostakis G E, et al. Dalton Trans., 2017, 46(45):15661-15665 doi: 10.1039/C7DT03149A
38. [38]
  Tziotzi T G, Kalofolias D A, Tzimopoulos D I, et al. Dalton Trans., 2015, 44(13):6082-6088 doi: 10.1039/C5DT00300H
39. [39]
  Liu J L, Wu J Y, Chen Y C, et al. Angew. Chem. Int. Ed., 2014, 53(47):12966-12970 doi: 10.1002/anie.201407799
40. [40]
  Chen S H, Mereacre V, Anson C E, et al. Dalton Trans., 2016, 45(22):9336-9344 doi: 10.1039/C6DT01364C
41. [41]
  Schmidt S F. M, Koo C, Mereacre V, et al. Inorg. Chem., 2017, 56(9):4796-4806
42. [42]
  Han H T, Li X L, Zhu X F, et al. Eur. J. Inorg. Chem., 2017(41):4879-4883
43. [43]
  Li J, Wei R M, Pu T C, et al. Inorg. Chem. Front., 2017, 4(1):114-122
44. [44]
  Peng Y, Mereacre V, Anson C E, et al. Dalton Trans., 2017, 46(16):5337-5343 doi: 10.1039/C7DT00548B
45. [45]
  De Souza M S, Briganti M, Reis S G, et al. Inorg. Chem., 2019, 58(3):1976-1987
46. [46]
  Huang G Z, Ruan Z Y, Zheng J Y, et al. Sci. China Chem., 2018, 61(11):1399-1404 doi: 10.1007/s11426-018-9310-y
47. [47]
  Chandrasekhar V, Bag P, Kroener W, et al. Inorg. Chem., 2013, 52(22):13078-13086 doi: 10.1021/ic4019025
48. [48]
  Zhao F H, Li H, Che Y X, et al. Inorg. Chem., 2014, 53(18):9785-9799 doi: 10.1021/ic501374q
49. [49]
  Jiang L, Liu Y, Liu X, et al. Dalton Trans., 2017, 46(37):12558-12573 doi: 10.1039/C7DT02351K
50. [50]
  Pei S M, Hu Z B, Chen Z L, et al. Dalton Trans., 2018, 47(6):1801-1807 doi: 10.1039/C7DT04003B
51. [51]
  Mahapatra P, Koizumi N, Kanetomo T, et al. New J. Chem., 2019, 43(2):634-643 doi: 10.1039/C8NJ03512A
52. [52]
  Wang H S, Yang F J, Long Q Q, et al. New J. Chem., 2017, 41(13):5884-5892 doi: 10.1039/C7NJ00459A
53. [53]
  Chen Y, Long Q Q, Hu Z B, et al. New J. Chem., 2019, 43(21):8101-8108 doi: 10.1039/C9NJ00892F
54. [54]
  Wu J F, Zhao L, Zhang L, et al. Angew. Chem. Int. Ed., 2016, 55(50):15574-15578 doi: 10.1002/anie.201609539
55. [55]
  Kühne I A, Magnani N, Mereacre V, et al. Chem Commun., 2014, 50(15):1882-1885 doi: 10.1039/c3cc46458j
56. [56]
  Vignesh K R, Langley S K, Murray K S, et al. Inorg. Chem., 2017, 56(5):2518-2532 doi: 10.1021/acs.inorgchem.6b02720
57. [57]
  Zou H H, Sheng L B, Liang F P, et al. Dalton Trans., 2015, 44(42):18544-18552 doi: 10.1039/C5DT03368C
58. [58]
  Zhang H F, Liu R, Zhang J, et al. CrystEngComm, 2016, 18(42):8246-8252 doi: 10.1039/C6CE01589A
59. [59]
  Wang H S, Yin C L, Hu Z Bo, et al. Dalton Trans., 2019, 48(27):10011-10022 doi: 10.1039/C9DT00774A
60. [60]
  Xu G F, Gamez P, Tang J K, et al. Inorg. Chem., 2012, 51(10):5693-5698 doi: 10.1021/ic300126q
61. [61]
  Vignesh K R, Langley S K, Murray K S, et al. Chem. Eur. J., 2017, 23(7):1654-1666 doi: 10.1002/chem.201604835
62. [62]
  Liu J L, Chen Y C, Zheng Y Z, et al. Chem. Sci., 2013, 4(8):3310-3316 doi: 10.1039/c3sc50843a
63. [63]
  Sun W B, Yan P F, Jiang S D, et al. Chem. Sci., 2016, 7(1):684-691 doi: 10.1039/C5SC02986D
64. [64]
  Oyarzabal I, Ruiz J, Ruiz E, et al. Chem. Commun., 2015, 51(62):12353-12356 doi: 10.1039/C5CC04495B
65. [65]
  Costes J P, Titos-Padilla S, Oyarzabal I, et al. Chem. Eur. J., 2015, 21(44):15785-15796 doi: 10.1002/chem.201501500
66. [66]
  Liu C M, Zhang D Q, Su J B, et al. Inorg. Chem., 2018, 57(17):11077-11086 doi: 10.1021/acs.inorgchem.8b01653
67. [67]
  Amjad A, Madalan A M, Andruh M, et al. Chem. Eur. J., 2016, 22(36):12849-12858 doi: 10.1002/chem.201601996
68. [68]
  Yin C L, Hu Z B, Long Q Q, et al. Dalton Trans., 2019, 48(2):512-522 doi: 10.1039/C8DT03849J
69. [69]
  Liu J L, Chen Y C, Tong M L. Chem. Soc. Rev., 2018, 47(7):2431-2453 doi: 10.1039/C7CS00266A
70. [70]
  Rinehart J D, Long J R. Chem. Sci., 2011, 2(11):2078-2085 doi: 10.1039/c1sc00513h
71. [71]
  Crawford V H, Richardson H W, Wasson J R, et al. Inorg. Chem., 1976, 15(9):2107-2110 doi: 10.1021/ic50163a019
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