Citation: RUAN Ding-Shan, LIN Bo, HU Guo-Rong, DU Ke, LIU Wei-Jian, CHEN Xi-Wen, XU Shuai-Jun, LUO Cui-Ping, MIAO Jian-Lin, CHEN Xi, LI Chang-Dong. Effect of Zr/W Co-doped on Morphology and Electrochemical Performance of LiNi_0.88Co_0.06Mn_0.06O₂ for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2289-2298. doi: 10.11862/CJIC.2020.263 shu

Effect of Zr/W Co-doped on Morphology and Electrochemical Performance of LiNi_0.88Co_0.06Mn_0.06O₂ for Lithium-Ion Batteries

RUAN Ding-Shan ^1,2,# ,
LIN Bo ^2,# ,
HU Guo-Rong ^1,, ,
DU Ke ¹ ,
LIU Wei-Jian ² ,
CHEN Xi-Wen ² ,
XU Shuai-Jun ² ,
LUO Cui-Ping ² ,
MIAO Jian-Lin ² ,
CHEN Xi ² ,
LI Chang-Dong ²

1.
School of Metallurgy and Environment, Central South University, Changsha 410083, China
2.
Guangdong Brunp Recycling Technology Co., Ltd., Foshan, Guangdong 528100, China

Corresponding author: HU Guo-Rong, 1044283793@qq.com
Received Date: 28 May 2020
Revised Date: 16 September 2020

Figures(10)

The precursor Ni_0.88Co_0.06Mn_0.06(OH)₂ was prepared by coprecipitation method. Ni-rich material with good primary particles dispersion were synthesized by high temperature solid-state sintering. The effects of ZrO₂ and WO₃ doped on the primary particles morphology and electrochemical properties of cathode materials was explored. The results showed that Zr doped had little effect on the morphology of LiNi_0.88Co_0.06Mn_0.06O₂ (NCM-Z), especially on the size of primary particles, but it could improve the cycle performance of the material. When W was introduced to form Zr and W co-doped, the primary particles of NCM-ZW obtained become smaller obviously, and the morphology of the material changed from dispersed primary particles to secondary aggregates, so W could inhibit the crystal growth. Furthermore, in order to synthesize Zr and W co-doped Ni-rich material with good primary particles dispersion, the influence of sintering temperature on the synthesis of Ni-rich material was studied. Finally, the Ni-rich material with primary particles dispersion morphology could be obtained by sintering at 900 ℃ for 12 hours. XRD results showed that Zr and W co-doped sample which was sintered at 900 ℃ had batter layered structure and lower cation mixing. The first discharge capacity of the sample was 203.7 mAh·g^-1 at 0.1C. In addition, the capacity was 151.2 mAh·g^-1 at 5C, after 100 cycles, the retention rate of discharge capacity was 84.6%.
- Li-ion battery,
- cathode material,
- primary particles,
- Zr-doped,
- W-doped
1. [1]
  HU Guo-Rong, LIU Qiang, DU Ke, et al. Chinese J. Inorg. Chem., 2012, 28(6):1171-1176
2. [2]
  Jo M, Noh M, Oh P, et al. Adv. Energy Mater., 2014, 4(13):13072-13078
3. [3]
  Du K, Hua C S, Tan C P, et al. J. Power Sources, 2014, 263(4):203-208
4. [4]
  Shi X, Wang C, Ma X, et al. Mater. Chem. Phys., 2009, 113(2):780-783
5. [5]
  ZHANG Yu, SU Zhi, PAN Hui. Chinese J. Inorg. Chem., 2015, 31(9):1827-1830
6. [6]
  Li X Q, Xiong X H, Wang Z X, et al. Trans. Nonferrous Met. Soc. China, 2014, 24(12):4023-4029 doi: 10.1016/S1003-6326(14)63564-0
7. [7]
  Yang Z R, Bao L Y, Li W K, et al. J. Alloys Compd., 2019, 789(15):736-743
8. [8]
  Gan Z G, Hu G R, Peng Z D, et al. Appl. Surf. Sci., 2019, 481:1228-1238 doi: 10.1016/j.apsusc.2019.03.116
9. [9]
  Zhao Z Y, Huang B, Wang M, et al. Solid State Ionics, 2019, 342:115065 doi: 10.1016/j.ssi.2019.115065
10. [10]
  Chen Y P, Zhang Y, Wang F, et al. J. Alloys Compd., 2014, 611:135-141 doi: 10.1016/j.jallcom.2014.05.068
11. [11]
  Xu Y, Li X H, Wang Z X, et al. Mater. Lett., 2015, 143:151-154 doi: 10.1016/j.matlet.2014.12.093
12. [12]
  Kong J Z, W S S, Tai G A, et al. J. Alloys Compd., 2016, 657:593-600 doi: 10.1016/j.jallcom.2015.10.187
13. [13]
  Song G W, Zhong H, Dai Y Y, et al. Ceram. Int., 2019, 45(6):6774-6781 doi: 10.1016/j.ceramint.2018.12.169
14. [14]
  Liang L W, Hu G R, Jiang F, et al. J. Alloys Compd., 2016, 657:570-581 doi: 10.1016/j.jallcom.2015.10.177
15. [15]
  Xie Z C, Zhang Y Y, Yuan A B, et al. J. Alloys Compd., 2019, 787:429-439 doi: 10.1016/j.jallcom.2019.02.127
16. [16]
  Lee S H, Yoon C S, Amine K, et al. J. Power Sources, 2013, 234:201-207 doi: 10.1016/j.jpowsour.2013.01.045
17. [17]
  Zhao R R, Liang J X, Huang J J, et al. J. Alloys Compd., 2017, 724:1109-1116 doi: 10.1016/j.jallcom.2017.05.331
18. [18]
  Gao S, Zhan X W, Cheng Y T. J. Power Sources, 2019, 410-411:45-52 doi: 10.1016/j.jpowsour.2018.10.094
19. [19]
  Chen Y X, Li Y J, Li W, et al. Electrochim. Acta, 2018, 281:48-59 doi: 10.1016/j.electacta.2018.05.154
20. [20]
  Park G T, Ryu H H, Park N Y, et al. J. Power Sources, 2019, 442:227242 doi: 10.1016/j.jpowsour.2019.227242
21. [21]
  He T, Chen L, Su Y F, et al. J. Power Sources, 2019, 441:227195 doi: 10.1016/j.jpowsour.2019.227195
22. [22]
  Yang Z R, Bao L Y, Li W K, et al. J. Alloys Compd., 2019, 789:736-743 doi: 10.1016/j.jallcom.2019.03.125
23. [23]
  Gupta A, Chemelewski W D, Mullins C B, et al. Adv. Mater., 2015, 27(39):6063-6067 doi: 10.1002/adma.201502256
24. [24]
  Wu F, Liu N, Chen L, et al. Nano Energy, 2019, 59:50-57 doi: 10.1016/j.nanoen.2019.02.027
25. [25]
  Yang F, Zhang Q G, Hu X H, et al. J. Power Sources, 2017, 353:323-332 doi: 10.1016/j.jpowsour.2017.04.002
26. [26]
  Zheng F H, Ou X, Pan Q C, et al. J. Power Sources, 2017, 346:31-39 doi: 10.1016/j.jpowsour.2017.02.036
27. [27]
  Fan X M, Hu G R, Zhang B, et al. Nano Engery, 2020, 70:104450
28. [28]
  Tu W Q, Pan X, Zheng X W, et al. J. Power Sources, 2017, 341:348-356 doi: 10.1016/j.jpowsour.2016.12.012
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
3. [3]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
7. [7]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
8. [8]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
9. [9]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
10. [10]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
11. [11]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
12. [12]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
13. [13]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
14. [14]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
15. [15]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
16. [16]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
17. [17]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
18. [18]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
19. [19]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
20. [20]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004

Get Citation

PDF

XML

Metrics

PDF Downloads(34)
Abstract views(2047)
HTML views(677)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Zr/W Co-doped on Morphology and Electrochemical Performance of LiNi0.88Co0.06Mn0.06O2 for Lithium-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Zr/W Co-doped on Morphology and Electrochemical Performance of LiNi_0.88Co_0.06Mn_0.06O₂ for Lithium-Ion Batteries