Citation: XU Li-Mei, HUANG Hua-Bin, SHEN Jin-Hai, YOU Qi-Hua. Synthesis of Zn-Doped BiOBr with Enhanced Photoreduction CO₂ Activity under Visible Light Irradiation[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2395-2403. doi: 10.11862/CJIC.2020.262 shu

Synthesis of Zn-Doped BiOBr with Enhanced Photoreduction CO₂ Activity under Visible Light Irradiation

College of Environment and Public Health, Xiamen Huaxia University, Xiamen, Fujian 361024, China

Corresponding author: XU Li-Mei, xlm@hxxy.edu.cn
Received Date: 6 June 2020
Revised Date: 17 September 2020

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The bismuth oxybromide (BiOBr) semiconductor has been used in photocatalytic CO₂ reduction for a long time, but the catalytic activity remains low. Herein, the Zn-doped BiOBr photocatalysts (called Zn-BiOBr) was synthesized by a simple hydrothermal method, which put out higher catalytic activity than pure BiOBr under visible light. The results showed that the synthesized 2% Zn-BiOBr exhibited the highest photocatalytic rate of 8.49 μmol·h^-1, which was 13 times higher than pure BiOBr. The enhancement mechanism of photocatalytic activity was also studied. Under visible light, Zn-BiOBr catalyst is excited and creates photo-induced electrons and holes, which effectively improve the conversion of CO₂ into CO. Doping of zinc provides BiOBr with a more suitable band gap and energy band defects, facilitates the separation of photogenerated charges, and reduces the recombination rate of photogenerated electrons, all of which contribute to the CO₂ conversion efficiency.
- Zn-doped BiOBr,
- semiconductors,
- photocatalyst,
- CO₂ reduction,
- visible light,
- energy storage and conversion
1. [1]
  Kong Z C, Liao J F, Dong Y J, et al. ACS Energy Lett., 2018, 3:2656-2662 doi: 10.1021/acsenergylett.8b01658
2. [2]
  Zhou M, Wang S B, Yang P J, et al. ACS Catal., 2018, 8:4928-4936 doi: 10.1021/acscatal.8b00104
3. [3]
  Wang Y X, Zhang Z Y, Zhang L R, et al. J. Am. Chem. Soc., 2018, 140:14595-14598 doi: 10.1021/jacs.8b09344
4. [4]
  Liu Y N, Miao C L, Yang P F, et al. Appl. Catal. B, 2019, 244:919-930 doi: 10.1016/j.apcatb.2018.12.028
5. [5]
  Ren S J, Shoemaker Weston R, et al. Fuel, 2019, 239:1125-1133 doi: 10.1016/j.fuel.2018.11.105
6. [6]
  García-López E, Marcì G, Pomilla F R, et al. Catal. Today, 2018, 313:100-105 doi: 10.1016/j.cattod.2018.01.030
7. [7]
  Kikkawa S, Teramura K, Asakura H, et al. J. Phys. Chem. C, 2018, 122:2132-2139
8. [8]
  Li R P, Ren H J, Ma W H, et al. Catal. Commun., 2018, 106:1-5 doi: 10.1016/j.catcom.2017.11.015
9. [9]
  Gao M C, Yang J X, Sun T, et al. Appl. Catal. B, 2019, 243:734-740 doi: 10.1016/j.apcatb.2018.11.020
10. [10]
  Gao M C, Zhang D F, Pu X P, et al. Mater. Lett., 2015, 140:31-34 doi: 10.1016/j.matlet.2014.10.032
11. [11]
  Wu D, Yue S T, Wang W, et al. Appl. Catal. B, 2016, 192:35-45 doi: 10.1016/j.apcatb.2016.03.046
12. [12]
  Wu D, Ye L Q, Ho Y Y, et al. Catal. Sci. Technol., 2017, 7:265-271 doi: 10.1039/C6CY02040B
13. [13]
  Kong X Y, Lee W P C, Ong W J, et al. ChemCatChem, 2016, 8:3074-3081 doi: 10.1002/cctc.201600782
14. [14]
  Bai Y, Chen T, Wang P Q, et al. Sol. Energy Mater. Sol. Cells, 2016, 157:406-414 doi: 10.1016/j.solmat.2016.07.001
15. [15]
  Liu Z L, Jin Y J, Teng F, et al. Catal. Commun., 2015, 66:42-45 doi: 10.1016/j.catcom.2015.03.017
16. [16]
  Guo J Q, Liao X, Lee M H, et al. Appl. Catal. B, 2019, 243:502-512 doi: 10.1016/j.apcatb.2018.09.089
17. [17]
  Jia H M, He W W, Zhang B B, et al. Appl. Surf. Sci., 2018, 441:832-840 doi: 10.1016/j.apsusc.2018.02.030
18. [18]
  Wang X Y, Zhang Z G, Huang Z F, et al. Mater. Res. Bull., 2019, 118:110-115
19. [19]
  Subha N, Mahalakshmi M, Myilsamy M, et al. Appl. Catal. A, 2018, 553:43-51
20. [20]
  Zhang G J, Su A T, Qu J W, et al. Mater. Res. Bull., 2014, 55:43-47 doi: 10.1016/j.materresbull.2014.04.012
21. [21]
  Ye L Q, Jin X L, Liu C, et al. Appl. Catal. B, 2016, 187:281-290 doi: 10.1016/j.apcatb.2016.01.044
22. [22]
  Djurišić A B, Leung Y H, Ching A M, et al. Mater. Horiz., 2014, 1:400-410 doi: 10.1039/c4mh00031e
1. [1]
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2. [2]
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13. [13]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Zn-Doped BiOBr with Enhanced Photoreduction CO2 Activity under Visible Light Irradiation

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Zn-Doped BiOBr with Enhanced Photoreduction CO₂ Activity under Visible Light Irradiation