Citation: DING Qi-Hui, LIU Yao-Yao, LI Lu-Chao, HUANG Yong-Qing, ZHAO Yue. Syntheses, Structures and Optical Band Gaps of Three Zn(Ⅱ)/Co(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2014-2022. doi: 10.11862/CJIC.2020.245 shu

Syntheses, Structures and Optical Band Gaps of Three Zn(Ⅱ)/Co(Ⅱ) Coordination Polymers

1.
Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology, College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemical and Chemical Engineering, Nanjing 210023, China

Corresponding author: HUANG Yong-Qing, yqhuangskd@163.com ZHAO Yue, zhaoyue@nju.edu.cn
Received Date: 7 May 2020
Revised Date: 14 September 2020

Figures(11)

Three new coordination polymers with formulas[Zn(L1)(L2)_0.5Cl]_n (1), [Co(L1)(L2)_0.5Cl]_n (2) and {[Zn(L1) (L3)]ClO₄·1.7H₂O}_n (3) have been prepared via the combination of zwitterionic carboxylic ligand with Zn(Ⅱ) and Co (Ⅱ) salts under the participation of two bridging imidazole-based isomers, where L1, L2 and L3 are 4-carboxy-1-(4-carboxybenzyl)-pyridinium, 1, 4-bis(imidazole-1-ylmethyl)benzene and 1, 3-bis(imidazole-1-ylmethyl)benzene, respectively. Complexes 1 and 2 are isostructural and feature an undulated 2D herringbone layer structure with (6, 3) topology, exhibiting a rare 2D→3D inclined polycatenated structure. Compared with 1 and 2, complex 3 displays 1D catenated chain structure, which are further assembled into 2D layer via abundant π-π interactions. It is noteworthy that 1~3 can all be considered as consisting of 1D[M(L1)]_n chains and bridging bis-imidazole-based ligands. For 1 and 2, the 1D[M(L1)]_n chains take helical form and bridging L2 ligands adopting Z-shape. In contrast, the 1D[M(L1)]_n chains in 3 exhibit zigzag form and bridging L3 ligands having C-configuration. The results reveal that different N-donor ancillary ligands and anions have a subtle effect on the final structures. The study of optical band gaps showed that the band gaps of 1~3 were 2.96, 1.72 and 3.16 eV, respectively, which indicates that 1~3 have properties of potential wide-band-gap semiconductors.CCDC: 1973985, 1; 1973986, 2; 1973987, 3.
- Zn(Ⅱ) complex,
- Co(Ⅱ) complex,
- coordination polymer,
- crystal structure,
- optical band gap
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1.
沈阳化工大学材料科学与工程学院沈阳 110142