Citation: DING Guo-Yu, GAO Yuan, LI Ya-Hui, ZHU Zhen, WANG Qiu-Lin, JING Xin-Guo, YAN Feng-Qian, XU Guo-Jun, YUE Zhi-Hao, LI Xiao-Min, SUN Fu-Gen. In Situ Reactive Coating of Fast Ionic Conductor LiTi₂(PO₄)₃ on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Materials for High-Performance Li-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(12): 2307-2314. doi: 10.11862/CJIC.2020.239 shu

In Situ Reactive Coating of Fast Ionic Conductor LiTi₂(PO₄)₃ on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Materials for High-Performance Li-Ion Batteries

Institute of Photovoltaics, Nanchang University, Nanchang 330031, China

Corresponding author: SUN Fu-Gen, sunfugen@ncu.edu.cn
Received Date: 23 June 2020
Revised Date: 26 July 2020

Figures(5)

A uniform fast ionic conductor LiTi₂(PO₄)₃ (LTP) coating layer on the surface of Ni-rich layered metal oxide LiNi_0.8Co_0.1Mn_0.1O₂ (LNCM811) cathode material, was constructed via an in situ reaction of the residual LiOH and Li₂CO₃ on the LNCM811 surface with the added C₈H₂₀O₄Ti and (NH₄)H₂PO₄. This in situ reactive coating approach is favorable to remove the undesired LiOH and Li₂CO₃ which are residual on the LNCM811 surface. Moreover, the obtained uniform LTP coating layers could not only protect the LNCM811 cathode materials from the sidereaction with the electrolytes, but also ensure the fast Li⁺ conductivity for the LNCM811 cathode materials during the charge and discharge cycling. Therefore, owing to the multifunctional effects of the LTP coating, the LTP coated LNCM811 cathode materials exhibited excellent cyclic stability and rate performances with a high initial capacity of 200.1 mAh·g^-1 at 0.2C, the high reversible capacities of 155.7 mAh·g^-1 after the 200th cycle at 0.2C, 126.4 mAh·g^-1 at 2C and 111.9 mAh·g^-1 at 5C.
- energy storage technology,
- lithium-ion battery,
- cathode materials,
- LiNi_0.8Co_0.1Mn_0.1O₂,
- LiTi₂(PO₄)₃ coating,
- fast ionic conductor
1. [1]
  XIONG Wen-Xu, ZHANG Xue-Qian, HUANG Wei-Wei. Chinese J. Inorg. Chem., 2020, 36(2):269-275
2. [2]
  Choi N S, Chen Z, Freunberger S A, et al. Angew. Chem. Int. Ed., 2012, 51(40):9994-10024 doi: 10.1002/anie.201201429
3. [3]
  Yi T F, Tao W, Chen B, et al. Electrochim. Acta, 2016, 188:686-695 doi: 10.1016/j.electacta.2015.12.036
4. [4]
  Zhao Y J, Li J, Dahn J R, et al. Chem. Mater., 2017, 29:5239-5248 doi: 10.1021/acs.chemmater.7b01219
5. [5]
  Zhang, L L, Peng G, Yang X L, et al. Vacuum, 2010, 84:1319-1322 doi: 10.1016/j.vacuum.2010.02.011
6. [6]
  Zhang L L, Wang J Q, Yang X L, et al. ACS Appl. Mater. Interfaces, 2018, 10(14):11663-11670 doi: 10.1021/acsami.7b19692
7. [7]
  Manthiram A, Song B H, Li W D. Energy Storage Mater., 2017, 6:125-139 doi: 10.1016/j.ensm.2016.10.007
8. [8]
  Liu Z L, Yu A S, Lee J Y. J. Power Sources, 1999, 81:416-419
9. [9]
  Ohzuku T, Makimura Y. Chem. Lett., 2001, 30(7):642-643 doi: 10.1246/cl.2001.642
10. [10]
  Scrosati B, Garche J. J. Power Sources, 2009, 195(9):2419-2430
11. [11]
  Mao H R, Zhang Y J, Dong P, et al. Int. J. Electrochem. Sci., 2016, 11(12):10536-10545
12. [12]
  Liu W, Oh P, Liu X, et al. Angew. Chem. Int. Ed., 2015, 54(15):4440-4457 doi: 10.1002/anie.201409262
13. [13]
  Kim J, Lee H, Cha H, et al. Adv. Energy Mater., 2018, 8(6):1702028 doi: 10.1002/aenm.201702028
14. [14]
  Yi T F, Li Y M, Yang S Y, et al. ACS Appl. Mater. Interfaces, 2016, 8:32349-32359 doi: 10.1021/acsami.6b11724
15. [15]
  Yi T F, Han X, Yang S Y, et al. Sci. China Mater., 2016, 59:618-628 doi: 10.1007/s40843-016-5097-7
16. [16]
  Chen M M, Zhao E Y, Chen D F, et al. Inorg. Chem., 2017, 56(14):8355-8362 doi: 10.1021/acs.inorgchem.7b01035
17. [17]
  Zhang D K, Liu Y, Wu L, et al. Electrochim. Acta, 2019, 328:135086 doi: 10.1016/j.electacta.2019.135086
18. [18]
  Hou P Y, Wang X Q, Song D W, et al. J. Power Sources, 2014, 265:174-181 doi: 10.1016/j.jpowsour.2014.04.107
19. [19]
  Sun Y K, Chen Z H, Noh H J, et al. Nat. Mater., 2012, 11:942-947 doi: 10.1038/nmat3435
20. [20]
  Li X L, He W X, Chen L, et al. Ionics, 2014, 20(6):833-840 doi: 10.1007/s11581-013-1041-8
21. [21]
  Xu Y D, Xiang W, Wu Z G, et al. Electrochim. Acta, 2018, 268:358-365 doi: 10.1016/j.electacta.2018.02.049
22. [22]
  Li J G, Zhang Q, Liu C, et al. Ionics, 2009, 15:493-496 doi: 10.1007/s11581-008-0263-7
23. [23]
  Gan Z G, Hu G R, Peng Z D, et al. Appl. Surf. Sci., 2019, 481:1228-1238 doi: 10.1016/j.apsusc.2019.03.116
24. [24]
  Dai S C, Yan G J, Wang L, et al. J. Electroanal. Chem., 2019, 847:113197 doi: 10.1016/j.jelechem.2019.113197
25. [25]
  Zhang B, Dong P Y, Tong H, et al. J. Alloys Compd., 2017, 706:198-204 doi: 10.1016/j.jallcom.2017.02.224
26. [26]
  Gao S, Zhan X W, Cheng Y T. J. Power Sources, 2019, 410-411:45-52 doi: 10.1016/j.jpowsour.2018.10.094
27. [27]
  Woo S G, Han J H, Kim K J, et al. Electrochim. Acta, 2015, 153:115-121 doi: 10.1016/j.electacta.2014.12.001
28. [28]
  LOU Tai-Ping, WANG Jia-Liang. Acta Phys.-Chim. Sin., 2007, 23(10):1642-1646
29. [29]
  Wang Y Q, Sun X R, Xiao R J, et al. Chin Phys. B, 2020, 29(3):038202 doi: 10.1088/1674-1056/ab7186
30. [30]
  Yoon C S, Ryu H H, Park G T, et al. J. Mater. Chem. A, 2018, 6(9):4126-4132 doi: 10.1039/C7TA11346C
31. [31]
  Li D C, Muta T, Zhang L Q, et al. J. Power Sources, 2004, 132:150-155 doi: 10.1016/j.jpowsour.2004.01.016
32. [32]
  Wang Q, Shen C H, Shen S Y, et al. ACS Appl. Mater. Interfaces, 2017, 9(29):24731 doi: 10.1021/acsami.7b06326
33. [33]
  Zhao E Y, Chen M M, Chen D F, et al. ACS Appl. Mater. Interfaces, 2015, 7:27096-27105 doi: 10.1021/acsami.5b08777
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
3. [3]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
4. [4]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
5. [5]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
6. [6]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
10. [10]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
11. [11]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
12. [12]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
13. [13]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
14. [14]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
15. [15]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
16. [16]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
17. [17]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
18. [18]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
19. [19]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
20. [20]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388

Get Citation

PDF

XML

Metrics

PDF Downloads(19)
Abstract views(1357)
HTML views(375)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

In Situ Reactive Coating of Fast Ionic Conductor LiTi2(PO4)3 on LiNi0.8Co0.1Mn0.1O2 Cathode Materials for High-Performance Li-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

In Situ Reactive Coating of Fast Ionic Conductor LiTi₂(PO₄)₃ on LiNi_0.8Co_0.1Mn_0.1O₂ Cathode Materials for High-Performance Li-Ion Batteries