Citation: ZHANG Zhao, SHEN Da, XIONG Xiao-Ying, YANG Hui, ZHANG Qi-Long, SHEN Qian-Hong. Preparation and Dielectric Properties of Ag-Loaded KTa_1-xNb_xO₃-BaTiO₃ Particle Doped P(VDF-TrFE-CTFE) Composite[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2048-2054. doi: 10.11862/CJIC.2020.228 shu

Preparation and Dielectric Properties of Ag-Loaded KTa_1-xNb_xO₃-BaTiO₃ Particle Doped P(VDF-TrFE-CTFE) Composite

State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: ZHANG Qi-Long, mse237@zju.edu.cn
Received Date: 5 March 2020
Revised Date: 2 July 2020

Figures(9)

An Ag-loaded KTa_1-xNb_xO₃-BaTiO₃ composite (Ag/KTN-BT) was prepared by light reduction method and then introduced into the P(VDF-TrFE-CTFE) matrix. The Ag/KTN-BT nanoparticles were uniformly dispersed in the polymer matrix without obvious pores and cracks, and the obtained nanocomposite film exhibited good flexibility. The introduction of Ag nanoparticles, on the one hand, introduces additional interfaces in the polymer matrix, leading to enhanced interface polarization and the dielectric constant of the composite; on the other hand, due to the quantum size effect and coulomb blockage effect of the silver nanoparticles, the composite maintains low dielectric loss. Typically, the dielectric constant of the composite filled with 20% (volume fraction) Ag/KTN-BT reached 125 at 100 Hz, in contrast to 37 for pristine P(VDF-TrFE-CTFE) polymer. Moreover, the composite remained low dielectric loss 0.12. Compared with the KTN-BT-based composite, Ag/KTN-BT-based composites also showed better dielectric properties.
- Ag,
- polymer-based,
- composite,
- interfacial polarization,
- dielectric property
1. [1]
  Chu S, Majumdar A. Nature, 2012, 488(7411):294-303 doi: 10.1038/nature11475
2. [2]
  Dang Z M, Yuan J K, Yao S H, et al. Adv. Mater., 2013, 25(44):6334-6365 doi: 10.1002/adma.201301752
3. [3]
  Wang Q, Zhu L. J. Polym. Sci. Part B, 2011, 49(20):1421-1429 doi: 10.1002/polb.22337
4. [4]
  Prateek V K, Thakur V K, Gupta R K. Chem. Rev., 2016, 116(7):4260-4317 doi: 10.1021/acs.chemrev.5b00495
5. [5]
  Yang C Y, Sun M Q, Wang X, et al. ACS Sustainable Chem. Eng., 2015, 3:2067-2076 doi: 10.1021/acssuschemeng.5b00334
6. [6]
  Chen T, Kong W H, Zhang Z W, et al. Nano Energy, 2018, 54:17-25 doi: 10.1016/j.nanoen.2018.09.059
7. [7]
  Dang Z M, Yuan J K, Zha J W, et al. Prog. Mater. Sci., 2012, 57(4):660-723 doi: 10.1016/j.pmatsci.2011.08.001
8. [8]
  Ye M, Sun Q, Chen X Q, et al. J. Am. Ceram. Soc., 2011, 4(10):3234-3236
9. [9]
  Zhang Q M, Wang L, Luo J, et al. Int. J. Appl. Ceram. Tech-nol., 2009, 7:E124-E128 doi: 10.1111/j.1744-7402.2009.02456.x
10. [10]
  Tang H, Sodano H A. Nano Lett., 2013, 13(4):1373-1379 doi: 10.1021/nl3037273
11. [11]
  Rahimabady M, Chen S, Yao K, et al. Appl. Phys. Lett., 2011, 99(14):142901 doi: 10.1063/1.3645619
12. [12]
  Dang Z M, Wang H Y, Xu H P. Appl. Phys. Lett., 2006, 89(11):112902 doi: 10.1063/1.2338529
13. [13]
  Tang H, Lin Y, Andrews C, et al. Nanotechnology, 2011, 22(1):015702
14. [14]
  Yang C, Song H S, Liu D B. Composites Part B, 2013, 50:180-186 doi: 10.1016/j.compositesb.2013.02.006
15. [15]
  SUI Yan, ZHOU Kai-Hao, HUANG Jian-Gen, et al. Chinese J. Inorg. Chem., 2017, 33(11):2024-2030
16. [16]
  Zhang X, Jiang J Y, Shen Z H, et al. Adv. Mater., 2018, 30(16):1707269 doi: 10.1002/adma.201707269
17. [17]
  Shen Y, Shen D S, Zhang X, et al. J. Mater. Chem. A, 2016, 4(21):8359-8365 doi: 10.1039/C6TA02186G
18. [18]
  Zou M Z, Ma Y, Yuan X, et al. J. Semicond., 2018, 39(1):11010
19. [19]
  Hu Y, Gu H, Hu Z, et al. Cryst. Growth Des., 2008, 8(3):832-837
20. [20]
  Chen G R, Wang X, Lin J Q, et al. J. Phys. Chem. C, 2016, 120(50):28423-28431 doi: 10.1021/acs.jpcc.6b09041
21. [21]
  Chen G R, Yang W L, Lin J Q, et al. J. Mater. Chem. C, 2017, 5(32):8135-8143 doi: 10.1039/C7TC01744H
22. [22]
  Zhang Z, Yang H, Wang H, et al. J. Mater. Sci.-Mater. Electron., 2019, 30(3):2501-2511 doi: 10.1007/s10854-018-0524-9
23. [23]
  Yang K, Huang X Y, He J L, et al. Adv. Mater. Interfaces, 2015, 2(17):1500361 doi: 10.1002/admi.201500361
24. [24]
  Lu J X, Moon K S, Xu J W, et al. J. Mater. Chem., 2006, 16(16):1543-1548 doi: 10.1039/b514182f
25. [25]
  Yang W L, Zhou Z X, Yang B, et al. Appl. Surf. Sci., 2012, 258(8):3986-3990 doi: 10.1016/j.apsusc.2011.12.081
26. [26]
  Lu Y, Claude J, Norena-Franco L E, et al. J. Phys. Chem. B, 2008, 112(34):10411-10416 doi: 10.1021/jp802413g
27. [27]
  Xu N X, Hu L, Zhang Q L, et al. ACS Appl. Mater. Interfaces, 2015, 7(49):27373-27381 doi: 10.1021/acsami.5b08987
28. [28]
  Luo H, Chen C, Zhou K C, et al. RSC Adv., 2015, 5(84):68515-68522 doi: 10.1039/C5RA11753D
29. [29]
  Yang L, Qiu J H, Ji H L, et al. Composites Part A, 2014, 65:125-134 doi: 10.1016/j.compositesa.2014.06.006
30. [30]
  Aleiner I L, Brouwer P W, Glazman L I. Phys. Rep., 2002, 358(5/6):309-440
31. [31]
  Konig D, Hiller D, Gutsch S, et al. Adv. Mater. Interfaces, 2014, 1(9):1400359 doi: 10.1002/admi.201400359
32. [32]
  Zhu X T, Yang J, Dastan D, et al. Composites Part A, 2019, 125:105521 doi: 10.1016/j.compositesa.2019.105521
1. [1]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
2. [2]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
3. [3]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
6. [6]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
7. [7]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
8. [8]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
9. [9]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
10. [10]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
11. [11]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
12. [12]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
13. [13]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
14. [14]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
15. [15]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
16. [16]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
17. [17]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
18. [18]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
19. [19]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
20. [20]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(741)
HTML views(94)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Dielectric Properties of Ag-Loaded KTa1-xNbxO3-BaTiO3 Particle Doped P(VDF-TrFE-CTFE) Composite

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Dielectric Properties of Ag-Loaded KTa_1-xNb_xO₃-BaTiO₃ Particle Doped P(VDF-TrFE-CTFE) Composite