Citation: WEI Wen-Chang, LIU Zheng, WEI Run-Zhi, TANG Qun, LIANG Chu-Xin, ZHANG Shu-Fen. Syntheses, Crystal Structure and Properties of Cu/Zn Complexes Based on 3, 4-Ethylenedioxythiophene Ring Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1891-1898. doi: 10.11862/CJIC.2020.217 shu

Syntheses, Crystal Structure and Properties of Cu/Zn Complexes Based on 3, 4-Ethylenedioxythiophene Ring Ligand

1.
College of Chemical and Biological Engineering, Guilin University of Technology, Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Guilin, Guangxi 541004, China
2.
Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Zheng, lisa4.6@163.com TANG Qun, tangq@glut.edu.cn
Received Date: 1 April 2020
Revised Date: 17 August 2020

Figures(6)

Two transition metal coordination polymer materials {[Cu₂(L₁)₂(L₂)(H₂O)₂(DMF)]·3H₂O}_n (1) (DMF=N, N-dimethylformamide) and {[Zn(L₁)(L₃)(H₂O)₂]·H₂O}_n (2), were successfully synthesized by solvothermal method with 3, 4-ethylenedioxythiophene-2, 5-dicarboxylic acid (H₂L₁), 2, 2'-bipyidine (L₂), and 4, 4'-bipyidine (L₃). The complexes were characterized by X-ray single crystal diffraction, infrared spectroscopy (IR), UV spectrum, fluorescence spectroscopy (FL) and thermogravimetric analysis (TG/DTG). The single crystal structure analysis shows that complex 1 is a two-dimensional (2D) layered structure formed by L₁^2- ligands bridging Cu²⁺ ions, and a three-dimensional (3D) network structure is further formed by hydrogen bonding interaction of L₂ ligands. Complex 2 forms one-dimensional (1D) chain by L₁^2- ligands connecting Zn²⁺ ions, and further bridging L₃ ligand to form 1D band structure, which is stacked to from 3D structure by the hydrogen-bonding and π-π stacking interaction between coordination water molecules and ligand oxygen atom. The FL and TG/DTG results indicate that complexes 1 and 2 have good thermal stability and fluorescence properties. The maximum emission peaks of complexes 1 and 2 are 364 and 365 nm, respectively. CCDC:1946117, 1; 1946113, 2.
- complex,
- 3, 4-ethylenedioxythiophene-2, 5-dicarboxylic acid,
- crystal structure,
- fluorescence,
- thermal stability
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