Citation: ZHONG Xin, HUANG Zi-Yang, ZHAO Meng-Yang. Preparation and Bioactivity Test in Vitro of HA/ZnO/SiO₂ Gradient Coating Materials[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2041-2047. doi: 10.11862/CJIC.2020.210 shu

Preparation and Bioactivity Test in Vitro of HA/ZnO/SiO₂ Gradient Coating Materials

College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Corresponding author: HUANG Zi-Yang, zyhuang@fjnu.edu.cn
Received Date: 3 February 2020
Revised Date: 30 May 2020

Figures(12)

Hydroxyapatite (HA), chitosan (CS), ZnO and SiO₂ suspensions were distributed by zonal electrophoresis, and then HA/CS/ZnO/SiO₂ composite coating material on the Ti-based surface was obtained by electrophoretic deposition in a reverse electric field subsequently. An HA/ZnO/SiO₂ coating material (Z1) was fabricated by calcination at 710℃ for 2 h. At the same time, another HA/ZnO/SiO₂ coating material (E1) was directly prepared only by electrophoretic deposition for comparison. Both Si and Zn elements with a gradient distribution in the radial direction of the coating was found by X-ray energy spectrum analysis, which indicates that Z1 has certain gradient properties. Then, scanning electron microscope, powder X-ray diffraction and Fourier transform infrared spectroscopy were used to characterize the two coating materials. It was found that Z1 has more excellent properties than E1, mainly manifested in the bonding strength of Z1 and Ti substrate up to 31.2 MPa, and the degree of carbonated apatite on the surface of Z1 was more complete after 14 days of culture in HEPES simulated body fluid. In addition, the bacteriostatic effect test of Z1 showed that the bacteriostatic rates of Z1 powder against E. coli and S. aureus were up to 81.7% and 89.4%, respectively.
- hydroxyapatite/ZnO/SiO₂ gradient coating material,
- bonding strength,
- bacteriostatic property,
- in vitro bioactivity
1. [1]
  Shen X, Yang Z, McCool E N, et al. Trac-Trends Anal. Chem., 2019, 120:115644 doi: 10.1016/j.trac.2019.115644
2. [2]
  Sequeira D B, Seabra C M, Palma P J, et al. J. Funct. Biomater., 2018, 9(4):74 doi: 10.3390/jfb9040074
3. [3]
  Furko M, Jiang Y, Wilkins T, et al. Mater. Sci. Eng. C, 2016, 62:249-259 doi: 10.1016/j.msec.2016.01.060
4. [4]
  Golovanova O A, Zaits A Ⅴ. Inorg. Mater., 2018, 54(11):1124-1130 doi: 10.1134/S0020168518110067
5. [5]
  Sadat-Shojai M, Khorasani M T, Dinpanah-Khoshdargi E, et al. Acta Biomater., 2013, 9(8):7591-7621 doi: 10.1016/j.actbio.2013.04.012
6. [6]
  O'Hare P, Meenan B J, Burke G A, et al. Biomaterials, 2010, 31(3):515-522 doi: 10.1016/j.biomaterials.2009.09.067
7. [7]
  XU Fu-Qiu, CHEN Hua-Jun, DING Wu-Xiu. Chinese J. Inorg. Chem., 2013, 29(12):2582-2586
8. [8]
  Hendi A A. J. Alloys Compd., 2017, 712:147-151 doi: 10.1016/j.jallcom.2017.04.021
9. [9]
  Azari R, Rezaie H R, Khavandi A. Ceram. Int., 2019, 45(14):17545-17555 doi: 10.1016/j.ceramint.2019.05.317
10. [10]
  Zhao Y, Lu M, Fan Z, et al. J. Eur. Ceram. Soc., 2020, 40(3):798-810 doi: 10.1016/j.jeurceramsoc.2019.10.037
11. [11]
  WANG Yan-Ling, DING Hong, HE Wei, et al. Journal of Oral Science Research, 2019, 35(11):1070-1073
12. [12]
  Tayyaba Q, Shahzad M, Butt A Q, et al. Surf. Coat. Technol., 2019, 375:197-204 doi: 10.1016/j.surfcoat.2019.07.014
13. [13]
  Huey D J, Hu J C, Athanasiou K A. Science, 2012, 338(6109):917-921 doi: 10.1126/science.1222454
14. [14]
  Dzherayan T G, Vanifatova N G, Fadeeva Ⅰ Ⅴ, et al. J. Anal. Chem., 2015, 70(5):608-614 doi: 10.1134/S1061934815050032
15. [15]
  Dutta D. Electrophoresis, 2018, 39(5/6):760-769
16. [16]
  HUANG Zi-Yang, ZHANG Lan, LIANG Guang-Chao. Acta Chim. Sinica, 2012, 70(3):30-35
17. [17]
  Kim H, Camata R P, Chowdhury S, et al. Acta Biomater., 2010, 6(8):3234-3241 doi: 10.1016/j.actbio.2010.02.031
18. [18]
  Li G, Liang G, Zhao S, et al. Adv. Appl. Ceram., 2015, 114(3):164-174 doi: 10.1179/1743676114Y.0000000210
19. [19]
  Applerot G, Lipovsky A, Dror R, et al. Adv. Funct. Mater., 2009, 19(6):842-852 doi: 10.1002/adfm.200801081
20. [20]
  Ravichandran K, Snega S, Begum N J, et al. Superlattices Microstruct., 2014, 69:17-28 doi: 10.1016/j.spmi.2014.01.020
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
3. [3]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
6. [6]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
7. [7]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
8. [8]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
9. [9]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
10. [10]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
11. [11]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
12. [12]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
13. [13]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
14. [14]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
15. [15]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
16. [16]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
17. [17]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
18. [18]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
19. [19]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
20. [20]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(593)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Bioactivity Test in Vitro of HA/ZnO/SiO2 Gradient Coating Materials

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Bioactivity Test in Vitro of HA/ZnO/SiO₂ Gradient Coating Materials