Citation: SUN Hui-Min, ZHOU Wen-Jun, HUANG Wei-Wei, WANG Li-Qiu. High Capacity Organic Cathode Calix[4]quinone in Ionic Liquids Electrolyte for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(9): 1701-1706. doi: 10.11862/CJIC.2020.199 shu

High Capacity Organic Cathode Calix[4]quinone in Ionic Liquids Electrolyte for Lithium-Ion Batteries

SUN Hui-Min ^1,2,# ,
ZHOU Wen-Jun ^1,# ,
HUANG Wei-Wei ^1,, ,
WANG Li-Qiu ^1,,

1.
School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China
2.
Qinhuangdao Vocational and Technical College, Qinhuangdao, Hebei 066100, China

Corresponding author: HUANG Wei-Wei, huangweiwei@ysu.edu.cn WANG Li-Qiu, liqiuwang@tom.com
Received Date: 18 March 2020
Revised Date: 2 July 2020

Figures(4)

In this work, calix^[4]quinone (C4Q), with a high theoretical capacity up to 446 mAh·g^-1, was selected as the cathode for lithium-ion batteries (LIBs). While the solubility issue in conventional organic electrolytes would prevent its electrochemistry properties from being fully exploited. To this end, the Li[TFSI]/[PY13] [TFSI] ([PY13] [TFSI]:N-methyl-N-propylpyrrolidiniumbis(trifluoromethanesulfonyl)amide) electrolyte was chosen to match C4Q cathode to assemble LIBs, which made positive progress in cycling stability and rate capability. At the current density of 0.1C, the discharge specific capacity was 280 mAh·g^-1 (77% of initial capacity) after 100 cycles, and the capacity retention rate was as high as 72% after 1 000 cycles. At 1C, the capacity could be still maintained at about 154 mAh·g^-1.
- electrochemistry,
- organic cathode,
- calix[4]quinone,
- ionic liquids,
- lithium-ion battery
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