Citation: SUN Zhi-Yu, CAO Shuai, HUANG Xiao-Qin, FAN Xiao-Ming, YANG Ze-Heng, ZHANG Wei-Xin. Preparation of Co₃O₄@NiMn-LDH Heterostructured Arrays as Efficient Oxygen Evolution Electrocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1899-1905. doi: 10.11862/CJIC.2020.188 shu

Preparation of Co₃O₄@NiMn-LDH Heterostructured Arrays as Efficient Oxygen Evolution Electrocatalyst

School of Chemistry and Chemical Engineering, Hefei University of Technology, Anhui Provincial Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei 230009, China

Corresponding author: FAN Xiao-Ming, xmfan@hfut.edu.cn ZHANG Wei-Xin, wxzhang@hfut.edu.cn
Received Date: 15 April 2020
Revised Date: 7 June 2020

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In this paper, we report the rational design and preparation of a new type of high-performance oxygen evolution electrocatalyst, namely 3D heterostructured Co₃O₄@NiMn-LDH (layered double metal hydroxide) arrays supported on Ni foam (Co₃O₄@NiMn-LDH/NF). It was prepared via facile two-step hydrothermal reactions. Compared with Co₃O₄, NiMn-LDH and traditional RuO₂ electrocatalysts, the as-prepared Co₃O₄@NiMn-LDH/NF presents better electrocatalytic oxygen evolution performance, achieving a low overpotential of 282 mV at 50 mA·cm^-2 with a Tafel slope of 64 mV·dec^-1 in 1 mol·L^-1 KOH solution. Through designing effective interface engineering, the Co₃O₄@NiMn-LDH/NF combines synergistically the excellent electrocatalytic activity of Co₃O₄ and NiMn-LDH. The Co₃O₄ nanowire array based on Ni foam as a core structure with abundant void spaces not only exposes more active sites, but also ensures easy diffusion of electrolyte and fast release of gas products. And the NiMn-LDH nanosheets on the Co₃O₄ nanowire array provide rich hydrophilic groups and active sites for easy access of water molecules, thus facilitating efficient oxygen evolution reaction.
- electrocatalytic oxygen evolution,
- Co₃O₄@NiMn-LDH,
- hydrothermal,
- heterostructure
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Preparation of Co₃O₄@NiMn-LDH Heterostructured Arrays as Efficient Oxygen Evolution Electrocatalyst