Citation: TANG Long, FU Yu-Hao, WANG Yi-Tong, WANG Huan-Huan, WANG Ji-Jiang, HOU Xiang-Yang, WANG Xiao. Three Complexes Constructed Using 2, 2'-Oxybis(benzoic acid) and N-Donor Ligands: Syntheses, Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1550-1556. doi: 10.11862/CJIC.2020.180 shu

Three Complexes Constructed Using 2, 2'-Oxybis(benzoic acid) and N-Donor Ligands: Syntheses, Structures and Fluorescent Properties

Yan'an University Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: TANG Long, ydtangl@126.com WANG Ji-Jiang, yadxwjj@126.com
Received Date: 24 December 2019
Revised Date: 26 March 2020

Figures(11)

Three new complexes[Zn(2, 2'-oba) (bipy)₂] ·2H₂O (1), [Pb(2, 2'-oba) (phen)]_n (2) and {[Pb(2, 2'-oba) (bimbp)]·H₂O}_n (3) (2, 2'-H₂oba=2, 2'-oxybis(benzoic acid), bipy=2, 2'-bipyridine, phen=1, 10-phenanthroline, bimbp=4, 4'-bis(imidazolyl)biphenyl) were synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction, thermogravimetric analyses, IR spectroscopy and elemental analysis. Complex 1 is a 0D structure, which is extended to a 2D supramolecular framework through aromatic π-π stacking interactions and strong intermolecular O-H…O hydrogen bonds. Complex 2 shows a 1D chain structure, which is expanded to a 2D layer structure through aromatic π-π stacking interactions. Complex 3 appears a 1D double chain structure, which is further extended to a 2D supramolecular framework through strong intermolecular O-H…O hydrogen bonds. Moreover, the solid-state fluorescent properties of 1~3 have also been investigated. According to the crystal structures, the TDDFT/6-31G(d) approach was applied to study the photoluminescence emission of 1, and the calculated results are in good agreement with the experimental results.
- complex,
- crystal structure,
- fluorescent properties,
- DFT studies
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