Citation: ZHAO Xiao-Bo, LI Yue-Jun, CAO Tie-Ping, SUN Da-Wei. Preparation and Photocatalytic Hydrogen Production of Bi/Yb³⁺, Er³⁺: TiO₂ Nanofibers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1535-1542. doi: 10.11862/CJIC.2020.174 shu

Preparation and Photocatalytic Hydrogen Production of Bi/Yb³⁺, Er³⁺: TiO₂ Nanofibers

1.
College of Chemistry, Baicheng Normal University, Baicheng, Jilin 137000, China
2.
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: LI Yue-Jun, bc640628@163.com
Received Date: 13 March 2020
Revised Date: 23 May 2020

Figures(11)

Bi deposited Yb³⁺, Er³⁺ codped TiO₂ nanofiber photocatalysts were synthesized from Yb³⁺ and Er³⁺ co-doped TiO₂ substrate by combining electrospinning technique and hydrothermal method. Using triethanolamine as a sacrificial agent, we studied the ultraviolet, visible, near infrared and full spectrum photocatalytic hydrogen production over Bi/Yb³⁺, Er³⁺:TiO₂. The results showed that the full-spectrum illumination for 5 h resulted in a hydrogen production rate of 1 650.3 μmol·g^-1·h^-1. As an emerging non-noble metal, Bi displays unique plasma photocatalytic or assisted photocatalytic properties. The advantages of Bi metal can be further combined with a rich energy level structure of rare earth elements and unique up-conversion luminescence properties. The double synergistic modification of TiO₂ can effectively improve the photocatalytic activity of TiO₂ nanofibers.
- metal Bi,
- Yb³⁺, Er³⁺ co-doped TiO₂ nanofibers,
- hydrothermal synthesis,
- photolysis
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Hydrogen Production of Bi/Yb3+, Er3+: TiO2 Nanofibers

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通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Hydrogen Production of Bi/Yb³⁺, Er³⁺: TiO₂ Nanofibers