Citation: LI Jin-Jin, LIU Cong-Cong, GUO Min, LI Shi-Ying, WU Zi-Chen, ZHAO Xiao-Li, YANG Xiao-Wei. Electrochemical Preparation of MoS₂ Intercalated Compound with Micron Size for Magnesium-Ion Storage[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1543-1549. doi: 10.11862/CJIC.2020.173 shu

Electrochemical Preparation of MoS₂ Intercalated Compound with Micron Size for Magnesium-Ion Storage

School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

Corresponding author: ZHAO Xiao-Li, zxl36@tongji.edu.cn
Received Date: 15 April 2020
Revised Date: 28 May 2020

Figures(7)

The micro-sized MoS₂ intercalated compound with the intercalant of 1-butyl-3-methyl-imidazolium cation (BMIM⁺) was prepared by a simple electrochemical method and used as cathode material of magnesium ion batteries. The MoS₂ intercalated compound (denoted as MoS₂-BMIM⁺) has an expanded interlayer spacing of 0.98 nm, which effectively reduced the insertion/extraction barrier of Mg²⁺ and provided abundant active sites for Mg²⁺ intercalation. Therefore, the MoS₂-BMIM+ deliverd a significantly improved charging capacity (101.93 mAh·g^-1 at 20 mA· g^-1, about 4 times as much as bulk MoS₂) and a good rate performance. We further show that this method can also be applied for the intercalation of 1-butyl-1-methylpyrrolidinium cation (Pyr₁₄⁺), which showed an interlayer spacing of 1.04 nm.
- magnesium ion battery,
- cathode material,
- molybdenum disulfide,
- electrochemical intercalation,
- interlayer spacing
1. [1]
  Dunn B, Kamath H, Tarascon J M, et al. Science, 2011, 334(6058):928-935 doi: 10.1126/science.1212741
2. [2]
  JIANG Ju-Hui, LI Pei-Pei, LIU Sheng-Nan, et al. Chinese J. Inorg. Chem., 2020, 35(12):2217-2225
3. [3]
  Aurbach D, Lu Z, Schechter A, et al. Nature, 2000, 407(6805):724-727 doi: 10.1038/35037553
4. [4]
  Yoo H D, Shterenberg I, Gofer Y, et al. Energy Environ. Sci., 2013, 6(8):2265-2279 doi: 10.1039/c3ee40871j
5. [5]
  Sun X Q, Bonnick P, Duffort V, et al. Energy Environ. Sci., 2016, 9(7):2273-2277 doi: 10.1039/C6EE00724D
6. [6]
  Canepa P, Gautam G S, Hannah D C, et al. Chem. Rev., 2017, 117(5):4287-4341 doi: 10.1021/acs.chemrev.6b00614
7. [7]
  Muldoon J, Bucur C B, Gregory T. Chem. Rev., 2014, 114(23):11683-11720 doi: 10.1021/cr500049y
8. [8]
  Levi E, Gofer Y, Aurbach D. Chem. Mater., 2010, 22(3):860-868
9. [9]
  Aurbach D, Suresh G S, Levi E, et al. Adv. Mater., 2007, 19(23):4260-4267 doi: 10.1002/adma.200701495
10. [10]
  Cheng Y W, Shao Y Y, Raju V, et al. Adv. Funct. Mater., 2016, 26(20):3446-3453 doi: 10.1002/adfm.201505501
11. [11]
  Wang L, Asheim K, Vullum P E, et al. Chem. Mater., 2016, 28(18):6459-6470 doi: 10.1021/acs.chemmater.6b01016
12. [12]
  Wang R C, Chung C C, Liu Y, et al. Langmuir, 2017, 33(37):9314-9323 doi: 10.1021/acs.langmuir.7b00705
13. [13]
  Wang F X, Wu X W, Li C Y, et al. Energy Environ. Sci., 2016, 9(12):3570-3611 doi: 10.1039/C6EE02070D
14. [14]
  Tao Z L, Xu L N, Gou X L, et al. Chem. Commun., 2004(18):2080-2081 doi: 10.1039/b403855j
15. [15]
  Xue X L, Chen R P, Yan C Z, et al. Adv. Energy Mater., 2019, 9(22):1900145(11 pages) doi: 10.1002/aenm.201900145
16. [16]
  Xie X Q, Makaryan T, Zhao M Q, et al. Adv. Energy Mater., 2016, 6(5):1502161(7 pages) doi: 10.1002/aenm.201502161
17. [17]
  Cook J B, Kim H S, Yan Y, et al. Adv. Energy Mater., 2016, 6(9):1501937(12 pages) doi: 10.1002/aenm.201501937
18. [18]
  Zhang H X, Liu Y, Jiang H, et al. Chem. Eng. Sci., 2019, 207:611-618 doi: 10.1016/j.ces.2019.06.043
19. [19]
  LI Mei-Juan, SHEN Shu-Yi, LUO Guo-Qiang, et al. Chinese J. Inorg. Chem., 2017, 33(9):1521-1526
20. [20]
  Xiong P, Ma R, Sakai N, et al. ACS Energy Lett., 2018, 3(4):997-1005 doi: 10.1021/acsenergylett.8b00110
21. [21]
  Xiao Y, Lee S H, Sun Y K. Adv. Energy Mater., 2017, 7(3):1601329(20 pages) doi: 10.1002/aenm.201601329
22. [22]
  Hu Z, Wang L, Zhang K, et al. Angew. Chem. Int. Ed., 2014, 126(47):13008-13012 doi: 10.1002/ange.201407898
23. [23]
  Xu K, Liao N B, Zhang M, et al. Nanoscale, 2020, 12(13):7098-7108 doi: 10.1039/C9NR09352D
24. [24]
  Yang S Q, Li D X, Zhang T R, et al. J. Phys. Chem. C, 2012, 116(1):1307-1312
25. [25]
  Tan Y H, Zhou F, Huang Z H, et al. ChemElectroChem, 2018, 5(7):996-1001 doi: 10.1002/celc.201701347
26. [26]
  Li X L, Li Y D. J. Phys. Chem. B, 2004, 108(37):13893-13900 doi: 10.1021/jp0367575
27. [27]
  Liang Y L, Feng R J, Yang S Q, et al. Adv. Mater., 2011, 23(5):640-643 doi: 10.1002/adma.201003560
28. [28]
  Liu Y C, Fan L Z, Jiao L F. J. Power Sources, 2017, 340:104-110 doi: 10.1016/j.jpowsour.2016.11.060
29. [29]
  Griffith K J, Wiaderek K M, Cibin G, et al. Nature, 2018, 559(7715):556-563 doi: 10.1038/s41586-018-0347-0
30. [30]
  Lu Z D, Liu N, Lee H W, et al. ACS Nano, 2015, 9(3):2540-2547 doi: 10.1021/nn505410q
31. [31]
  Liang Y L, Yoo H D, Li Y F, et al. Nano Lett., 2015, 15(3):2194-2202 doi: 10.1021/acs.nanolett.5b00388
32. [32]
  Wang C, He Q Y, Halim U, et al. Nature, 2018, 555(7695):231-236 doi: 10.1038/nature25774
33. [33]
  Li Y, Liang Y, Hernandez F C, et al. Nano Energy, 2015, 15:453-461 doi: 10.1016/j.nanoen.2015.05.012
34. [34]
  Shi Z T, Kang W, Xu J, et al. Nano Energy, 2016, 22:27-37 doi: 10.1016/j.nanoen.2016.02.009
35. [35]
  Lin Z, Liu Y, Halim U, et al. Nature, 2018, 562(7726):254-258 doi: 10.1038/s41586-018-0574-4
36. [36]
  Xu M, Lei S L, Qi J, et al. ACS Nano, 2018, 12(4):3733-3740 doi: 10.1021/acsnano.8b00959
37. [37]
  Liu Y C, Jiao L F, Wu Q, et al. Nanoscale, 2013, 5(20):9562-9567 doi: 10.1039/c3nr02850j
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Electrochemical Preparation of MoS2 Intercalated Compound with Micron Size for Magnesium-Ion Storage

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Electrochemical Preparation of MoS₂ Intercalated Compound with Micron Size for Magnesium-Ion Storage