Citation: ZHOU Yong-Hui, XU Qiu-Lei, LIU Chen-Lu, XU Jing-Jing. Synthesis and Opto-electronic Property of Three Green Iridium（Ⅲ） Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1267-1274. doi: 10.11862/CJIC.2020.165 shu

Synthesis and Opto-electronic Property of Three Green Iridium（Ⅲ） Complexes

ZHOU Yong-Hui ^1,#,, ,
XU Qiu-Lei ^2,#,, ,
LIU Chen-Lu ¹ ,
XU Jing-Jing ¹

1.
Collaborative Innovation Center for Atmospheric Environment and Equipment Technology, College of Chemistry and Materials, Nanjing University of Information Science&Technology, Nanjing 210044, China
2.
Key Lab for Special Functional Materials of Ministry of Education, College of Materials, Henan University, Kaifeng, Henan 475004, China

Corresponding author: ZHOU Yong-Hui, 002083@nuist.edu.cn; qiuleixu@163.com XU Qiu-Lei, qiuleixu@163.com
Received Date: 11 November 2019
Revised Date: 10 April 2020

Figures(5)

This work reports the synthesis and properties of three iridium(（Ⅲ）) complexes ((tfmppy)₂Ir(F-tpip), (tfmppy)₂Ir (MeO-tpip) and (tfmppy)₂Ir(tnin)) with 2-(4-(trifluoromethyl)phenyl)pyridine (tfmppy) as main ligand and tetra(4-fluoropheny) imidodiphosphinate (F-tpip), tetra(4-methoxypheny)imidodiphosphinate (MeO-tpip), tetra(naphthalen-1-yl) imidodiphosphinate (tnin) as ancillary ligands, respectively. Their structures were confirmed by ¹H NMR, MS (MALDI-TOF), elemental and single crystal analysis. Both (tfmppy)₂Ir(F-tpip) and (tfmppy)₂Ir(MeO-tpip) complexes belong to P1 space group of triclinic crystal system. The complex (tfmppy)₂Ir(tnin) belongs to R3c space group of trigonal crystal system. All the complexes are green materials with similar emission color and photoluminescence quantum efficiency ((tfmppy)₂Ir(F-tpip):λ_em=526 nm, Φ=0.52; (tfmppy)₂Ir(MeO-tpip):λ_em=523 nm, Φ=0.44; (tfmppy)₂Ir (tnin):λ_em=522 nm, Φ=0.48). In addition, the excited state lifetimes of (tfmppy)₂Ir(F-tpip), (tfmppy)₂Ir(MeO -tpip) and (tfmppy)₂Ir(tnin) were 2.51, 2.00 and 3.88 μs, respectively. Furthermore, they all showed good reversible redox peaks in the cyclic voltammetry curves, and their energy levels were also calculated ((tfmppy)₂Ir(F-tpip):E_HOMO=-5.67 eV, E_LUMO=-3.29 eV; (tfmppy)₂Ir(MeO-tpip):E_HOMO=-6.08 eV, E_LUMO=-3.61 eV; (tfmppy)₂Ir(tnin):E_HOMO=-5.69 eV, E_LUMO=-3.22 eV).
- iridium(Ⅲ) complex,
- phosphorescence material,
- green emission,
- crystal structure,
- electrochemical property
1. [1]
  Uoyama H, Goushi K, Shizu K, et al. Nature, 2012, 492:234238
2. [2]
  Baldo M A, O'Brien D F, You Y, et al. Nature, 1998, 395:151-154 doi: 10.1038/25954
3. [3]
  Ma Y, Zhang H, Shen J, et al. Synth. Met., 1998, 94:245-248 doi: 10.1016/S0379-6779(97)04166-0
4. [4]
  Yang X, Zhou G, Wong W Y. Chem. Soc. Rev., 2015, 44:84848575
5. [5]
  Li T Y, Wu J, Wu Z G, et al. Coord. Chem. Rev., 2018, 374:55-91 doi: 10.1016/j.ccr.2018.06.014
6. [6]
  LI Chun-Xiang, HU Jia-Wei, SUN Pei-Pei, et al. Chinese J. Inorg. Chem., 2007, 23:392-396 doi: 10.3321/j.issn:1001-4861.2007.03.004
7. [7]
  MA Ting-Chun, LIU Shun-Juan, TAO Peng, et al. Chinese J. Inorg. Chem., 2015, 31:1034-1040
8. [8]
  ZHAO Xue-Sen, CUI Rong-Zhen, LI YunHui, et al. Chinese Journal of Applied Chemistry, 2016, 33:1002-1008
9. [9]
  LIAO Zhang-Jin, ZHU Tong-Jun, MI BaoXiu, et al. Prog. Chem., 2011, 23:16271643
10. [10]
  ZHANG Li-Ying, LI Bin, LIU Xiu-Ying, et al. Chinese Journal of Luminescence, 2012, 33:166-170
11. [11]
  Adachi C, Baldo M A, Thompson M E, et al. J. Appl. Phys., 2001, 90:5048-5051 doi: 10.1063/1.1409582
12. [12]
  Fan C, Zhu L, Jiang B, et al. J. Phys. Chem. C, 2013, 117:19134-19141 doi: 10.1021/jp406220c
13. [13]
  Liu X, Yao B, Zhang Z, et al. J. Mater. Chem. C, 2016, 4:5787-5794 doi: 10.1039/C6TC01270A
14. [14]
  Adachi C, Baldo M A, Forrest S R. Appl. Phys. Lett., 2001, 79:2082-2084 doi: 10.1063/1.1400076
15. [15]
  Holmes R J, Forrest S R, Tung Y J, et al. Appl. Phys. Lett., 2003, 82:2422-2424 doi: 10.1063/1.1568146
16. [16]
  Zhu Y C, Zhou L, Li H Y, et al. Adv. Mater., 2011, 23:40414046
17. [17]
  TENG Ming-Yu, XU Qiu-Lei, LI HongYan, et al. Chinese Journal of Luminescence, 2013, 34:92-97
18. [18]
  ZHANG Song, XUE Li-Sha, WU Chen, et al. Chinese J. Inorg. Chem., 2014, 30:134-141
19. [19]
  ZHOU Yong-Hui, KONG Qing-Gang, WANG Zheng-Mei, et al. Chinese J. Inorg. Chem., 2014, 30:2288-2294
20. [20]
  Niu Z G, Chen J, Tan P, et al. Dalton Trans., 2018, 47:80328040
21. [21]
  Han H B, Cui R Z, Jing Y M, et al. J. Mater. Chem. C, 2017, 5:8150-8159 doi: 10.1039/C7TC02117H
22. [22]
  Jing Y M, Wang F Z, Zheng Y X, et al. J. Mater. Chem. C, 2017, 5:3714-3724 doi: 10.1039/C7TC00348J
23. [23]
  SAINT-Plus, Ver. 6.02, Bruker Analytical X-ray System:Madison, WI, 1999.
24. [24]
  Sheldrick G M. SADABS, an Empirical Absorption Correction Program, Bruker Analytical X -ray Systems, Madison, WI, 1996.
25. [25]
  Sheldrick G M. SHELXTL-97, University of Göttingen, Germany, 1997.
26. [26]
  Miyaura N, Suzuki A. Chem. Rev., 1995, 95:2457-2483 doi: 10.1021/cr00039a007
27. [27]
  Su Y J, Huang H L, Li C L. Adv. Mater., 2003, 15:884-888 doi: 10.1002/adma.200304630
28. [28]
  Thelakkat M, Schmidt H W. Adv. Mater., 1998, 10:219-223 doi: 10.1002/(SICI)1521-4095(199802)10:3<219::AID-ADMA219>3.0.CO;2-6
29. [29]
  Ashraf R S, Shahid M, Klemm E, et al. Macromol. Rapid Commun., 2006, 27:1454-1459 doi: 10.1002/marc.200600314
30. [30]
  Zhu R, Wen G A, Feng J C, et al. Macromol. Rapid Commun., 2005, 26:1729-1735 doi: 10.1002/marc.200500412
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1.
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