Citation: TIAN Hai, ZHONG Yan-Jun, WU Zhen-Guo, KONG Xing-Jian, YANG Xiu-Shan, GUO Xiao-Dong, WANG Xin-Long, ZHONG Ben-He. Synthesis and Lithium Storage Properties of Hollow Hierarchical Structure Fe₃O₄@C/rGO Composites[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1309-1317. doi: 10.11862/CJIC.2020.151 shu

Synthesis and Lithium Storage Properties of Hollow Hierarchical Structure Fe₃O₄@C/rGO Composites

School of Chemical Engineering, Sichuan University, Engineering Research Center of Comprehensive Utilization and Clean Processing of Phosphorus Resources of Ministry of Education, Chengdu 610065, China

Corresponding author: KONG Xing-Jian, kongxingjian@scu.edu.cn
Received Date: 6 February 2020
Revised Date: 9 April 2020

Figures(7)

The Fe₃O₄@C/rGO composite was synthesized using graphene oxide (GO) as the substrate, Fe(NO₃)₃·9H₂O, isopropanol and glycerol as the raw materials by solvothermal method and subsequent heat treatment process, and it succeeded in realizing the in-situ growth of carbon-coated hierarchical Fe₃O₄ hollow spheres on graphene oxide sheets. The physicochemical properties and lithium storage properties of Fe₃O₄@C/rGO materials were analyzed by X-ray diffractometer (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), galvanostatic discharge-charge, etc. The results showed that the composite still has the reversible capacity of 437.7 mAh·g^-1 under the current density of 5.0 A·g^-1, and the discharge specific capacity of 587.3 mAh·g^-1 after 200 cycles at 1.0 A·g^-1. This is mainly attributed to the introduction of reduced graphene oxide (rGO) which improves the overall structural stability and electrical conductivity of carbon-coated Fe₃O₄ hierarchical hollow spheres.
- Fe₃O₄@C/rGO hierarchical hollow sphere,
- solvothermal,
- anode material,
- lithium ion battery
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Synthesis and Lithium Storage Properties of Hollow Hierarchical Structure Fe₃O₄@C/rGO Composites