Citation: LIANG Xi-Tong, XUE Dong-Feng. In Situ Electrochemical Synthesis of Fe-Based Electrode for Supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1393-1400. doi: 10.11862/CJIC.2020.138 shu

In Situ Electrochemical Synthesis of Fe-Based Electrode for Supercapacitors

LIANG Xi-Tong ^1,2 ,
XUE Dong-Feng ^1,2,,

1.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
2.
University of Science and Technology of China, Hefei 230026, China

Corresponding author: XUE Dong-Feng, Dongfeng.Xue@sdu.edu.cn
Received Date: 28 December 2019
Revised Date: 29 March 2020

Figures(6)

This work adopts the colloidal nanoparticles as a model for research due to the prominent specific surface area of colloidal nanoparticles. There was a hypothesis that cations uniformly distributed in the conductive carbon and binder. Electrolyte ion can interact with cations to form reactive colloidal clusters in situ. Herein, the electrochemical method was adapted to synthesize different iron based electrode materials by the changes of electrolyte. Febased electrodes exhibited specific capacitances of 1 113, 927 and 755 F·g^-1 in KOH, NaOH and LiOH aqueous electrolyte, respectively. A novel type of colloid systems with adjustable structure was built, achieving multiscale controllable regulation of colloid structure and material performance. By extending the colloid model, a novel method of in situ composition adjustment to cross-scale control of material properties was provided.
- electrochemistry,
- synthesis design,
- iron oxide,
- electrode materials,
- supercapacitor
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