Citation: LI Shi-Xiong, HUANG Feng-Lan, MO Qiao-Ling, LIAO Bei-Ling. Synthesis, Characterization and Photocatalytic Mechanism of Hydroxyl Modified MOFs[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(7): 1401-1412. doi: 10.11862/CJIC.2020.135 shu

Synthesis, Characterization and Photocatalytic Mechanism of Hydroxyl Modified MOFs

1.
School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou, Guangxi 543002, China
2.
School of Chemistry and Biological Engineering, Hechi University, Hechi, Guangxi 546300, China

Corresponding author: LI Shi-Xiong, lsx1324@163.com LIAO Bei-Ling, liaobeiling1324@163.com
Received Date: 2 February 2020
Revised Date: 23 March 2020

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In this work, metal organic framework materials (MOFs) photocatalysts with large specific surface area and easy structure modification are synthesized:MIL-101(Cr) and MIL-101(Cr)-2OH. The structures of MIL-101(Cr) and MIL-101(Cr)-2OH photocatalysts were characterized by FT-IR, X-ray powder diffraction (PXRD), and X-ray photoelectron spectroscopy (XPS). The UV-visible diffuse reflectance spectroscopy (UV-Vis DRS), ζ potential, and electrospray ionization mass spectrometry (ESI-MS) were used to systematically analyze the effect of electron donating groups in the MOFs on photocatalytic degradation of methylene blue (MB). It was found that the two hydroxyl groups that do not participate in MIL-101(Cr)-2OH can affect the absorption of light through the action of ligandmetal charge transfer (LMCT), thereby regulating the photocatalytic degradation rate.
- MOFs,
- photocatalysis,
- mechanism,
- synthesis design,
- pollution
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沈阳化工大学材料科学与工程学院沈阳 110142