Citation: GAO Xian-Long, MO Wen-Long, MA Feng-Yun, FAN Xing. Effect of Promoter on the Ni-Al Alloy & the Corresponding Raney-Ni Catalyst and Hydrogenation Performance of 1, 4-Butylenediol[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 958-968. doi: 10.11862/CJIC.2020.102 shu

Effect of Promoter on the Ni-Al Alloy & the Corresponding Raney-Ni Catalyst and Hydrogenation Performance of 1, 4-Butylenediol

Key Laboratory of Coal Clean Conversion & Chemical Engineering Process(Xinjiang Uyghur Autonomous Region), College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China

Corresponding author: MO Wen-Long, mowenlong@xju.edu.cn
Received Date: 19 December 2019
Revised Date: 13 March 2020

Figures(13)

Three promoters (MgO, CuO, Co₂O₃) were introduced individually into the commercial Ni-Al alloy powder by impregnation method, and the modified alloys were leached by 10%(w/w) NaOH solution to prepare Raney-Ni catalysts. Effect of promoter on the elemental composition, crystal structure, pore structure, surface morphology and surface acidity of the Ni-Al alloy and the corresponding Raney-Ni catalyst was investigated by energy dispersive X-ray (EDX), X-ray diffraction (XRD), N₂ adsorption-desorption, transmission electron microscope (TEM), NH₃ temperature programmed desorption (NH₃-TPD) and X-ray photoelectron spectroscopy (XPS) methods. Results showed that the element content, specific surface area and surface morphology of the catalyst modified by different promoter proposed significant difference. Large amount of Ni- the active component on the Cu-modified catalyst was detected with the content of about 90%(w/w), showing excellent dispersion, and the catalyst presented small average pore size (3.87 nm). Evaluation results showed that the catalyst displayed well hydrogenation performance, with 1, 4-butenediol (BED) conversion of 100%, both 1, 4-butanediol (BDO) selectivity and yield of 59.62%, which was related to the high Ni content, the moderate amount of acid sites and the small Cu crystal for improving Ni dispersion without serious sintering by the "confinement effect".
- Raney-Ni catalyst,
- 1, 4-butenediol,
- 1, 4-butanediol,
- promoter,
- hydrogenation
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