Citation: GAO Chuan-Hui, DONG Ya-Jie, REN Xiu, CHEN Ying, WANG Hui-Zi, HU Zun-Fu, WANG Jing, LIU Yue-Tao. Hydration Mechanism and Stability Regulation of Hemihydrate Calcium Sulfate Whiskers[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(5): 908-920. doi: 10.11862/CJIC.2020.099 shu

Hydration Mechanism and Stability Regulation of Hemihydrate Calcium Sulfate Whiskers

GAO Chuan-Hui ¹ ,
DONG Ya-Jie ¹ ,
REN Xiu ¹ ,
CHEN Ying ¹ ,
WANG Hui-Zi ¹ ,
HU Zun-Fu ² ,
WANG Jing ¹ ,
LIU Yue-Tao ^1,,

1.
State Key Laboratory Base for Eco-Chemical Engineering in College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China
2.
College of Materials Science and Engineering, Linyi University, Linyi, Shandong 276000, China

Corresponding author: LIU Yue-Tao, yuetaoliu@qust.edu.cn
Received Date: 26 July 2019
Revised Date: 5 March 2020

Figures(12)

Hydration mechanism of hemihydrate calcium sulfate whisker (HCSW) was studied by discussing the change of morphology and crystal form in the storage process in the air, and the regulation of stability by different treatment methods was analyzed. It is found that the hydration of HCSW was caused by -OH group, Ca²⁺ active site at the surface and the internal channel inside of the whisker. Calcination and diol modification could improve the water resistance of calcium sulfate whisker. The experimental results indicate that after calcination, the hemihydrate calcium sulfate whisker are transformed into anhydrous soluble calcium sulfate whiskers and anhydrous dead calcium sulfate whiskers, the internal channels easy to hydration disappear, and the water resistance is enhanced. In the hydrothermal synthesis process, the addition of binary alcohol was beneficial to the adsorption of alcohol hydroxyl on the (200), (020) and (220) surfaces of HCSW, preventing the adsorption of hydroxyl in H₂O molecules on the whisker surface, and further improving the water resistance of the whisker. When the additive was triethylene glycol (TEG) and the concentration was 18.8 mmol·L^-1, the water resistance stability of HSCW in the air was not less than 7 days.
- hemihydrate calcium sulfate whisker,
- hydration,
- calcination,
- triethylene glycol
1. [1]
  Zhao W P, Gao C H, Guo F R, et al. Res. Chem. Intermed., 2016, 42(4):2953-2961
2. [2]
  Wang Y Q, Li Y C, Yuan A, et al. Cryst. Res. Technol., 2015, 49(10):800-807 doi: 10.1002/crat.201400155
3. [3]
  Mao X L, Song X F, Lu G M, et al. Ind. Eng. Chem. Res., 2014, 53(45):17625-17635 doi: 10.1021/ie5030134
4. [4]
  GAO Chuan-Hui, WANG Chuan-Xing, WU Yu-Min, et al. Chinese J. Inorg. Chem., 2012, 28(10):2198-2204
5. [5]
  Hong T Z, Lv Z H, Liu X, et al. Mater. Des., 2016, 107:117-122 doi: 10.1016/j.ygyno.2016.05.006
6. [6]
  Chang M P, Sung Y C, Su H C, et al. Ceram. Int., 2015, 41(1):1155-1162 doi: 10.1016/j.ceramint.2014.09.043
7. [7]
  Mcquinn M W, Orellana B R, Puleo D A. J. Oral Maxillofac. Surg., 2014, 72(9):e209-e210 doi: 10.1007/s11164-015-2189-9
8. [8]
  Woo K M, Jung H M, Oh J H, et al. Biomaterials, 2015, 39:1-14 doi: 10.1016/j.biomaterials.2014.10.054
9. [9]
  Xu A Y, Li H P, Luo K B, et al. Res. Chem. Intermed., 2011, 37(2/3/4/5):449-455 doi: 10.1007/s11164-011-0283-1
10. [10]
  Feng X, Zhang Y, Wang G L, et al. Powder Technol., 2015, 271:1-6 doi: 10.1016/j.powtec.2014.11.015
11. [11]
  Liu J Y, Ren L, Wei Q, et al. Polym. Compos., 2012, 33(4):501-508 doi: 10.1002/pc.22171
12. [12]
  Wang J C, Tang L J, Wu D, et al. Polym. Polym. Compos., 2012, 20(5):453-461 doi: 10.1177/096739111202000505
13. [13]
  Wang J C, Pan X C, Xue Y, et al. J. Elastomers Plast., 2012, 44(1):55-66 doi: 10.1177/0095244311414161
14. [14]
  Hou S C, Wang J, Wang X X, et al. Langmuir, 2014, 30(32):9804-9810 doi: 10.1021/la502451f
15. [15]
  YANG Hui, ZHANG Ling-Jie, GUO Xing-Zhong, et al. Chinese J. Inorg. Chem., 2012, 28(1):153-158
16. [16]
  Feldmann T, Demopoulos G P. J. Chem. Technol. Biotechnol., 2014, 89(10):1523-1533 doi: 10.1002/jctb.4231
17. [17]
  Wang T X, Colfen H, Antonietti M. J. Am. Chem. Soc., 2005, 127(10):3246-3247 doi: 10.1021/ja045331g
18. [18]
  Feldmann T, Demopoulos G P. Hydrometallurgy, 2015, 155(1):20-28 doi: 10.1016/j.hydromet.2015.03.019
19. [19]
  Guan B H, Yang L C, Wu Z B, et al. Fuel, 2009, 88(7):1286-1293
20. [20]
  Wang X, Jin B, Yang L S, et al. Cryst. Res. Technol., 2015, 50(8):633-640
21. [21]
  Jiang G M, Wang H, Chen Q S, et al. Fuel, 2016, 174:235-241
22. [22]
  Feldmann T, Demopoulos G P. Ind. Eng. Chem. Res., 2013, 52(19):6540-6549 doi: 10.1021/ie302933v
23. [23]
  Han Q, Luo K B, Li H P, et al. Particuology, 2014, 17(6):131-135 doi: 10.1016/j.partic.2014.02.008
24. [24]
  Wang X, Yang L S, Zhu X F, et al. Particuology, 2014, 17(6):42-48 doi: 10.1016/j.partic.2013.12.001
25. [25]
  Chen Q, Jiang G, Jia C, et al. CrystEngComm, 2015, 17(44):8549-8554 doi: 10.1039/c5ce01271f
26. [26]
  Zhao W P, Wu Y M, Xu J, et al. RSC Adv., 2015, 5(62):50544-50548
27. [27]
  Saha A, Lee J, Pancera S M, et al. Langmuir, 2012, 28(30):11182-11187 doi: 10.1021/la3024474
28. [28]
  WANG Yu-Bin. Thesis for the Doctorate of Northeast University. 2008.
29. [29]
  Lewry A J, Williamson J. J. Mater. Sci., 1994, 29(23):6085-6090 doi: 10.1007/BF00354546
30. [30]
  Anto P L, Anto R J, Varghese H T, et al. J. Raman Spectrosc., 2010, 40(12):1810-1815 doi: 10.1002/jrs.2323
31. [31]
  Sutter B, Dalton J B, Ewing S A, et al. J. Geophys. Res. G:Biogeosci., 2015, 112(G4):145-151 doi: 10.1029/2006JG000313@10.1002/(ISSN)2169-8961.ATACAMA1
1. [1]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
2. [2]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
3. [3]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
4. [4]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
5. [5]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
6. [6]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
11. [11]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
12. [12]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
13. [13]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
14. [14]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
15. [15]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
16. [16]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
17. [17]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
18. [18]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
19. [19]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
20. [20]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(1141)
HTML views(157)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142